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In-situ U-Pb dating of Ries Crater lacustrine carbonates (Miocene, South-West Germany): Implications for continental carbonate chronostratigraphy
Earth and Planetary Science Letters ( IF 5.3 ) Pub Date : 2021-06-07 , DOI: 10.1016/j.epsl.2021.117011
Damaris Montano , Marta Gasparrini , Axel Gerdes , Giovanna Della Porta , Richard Albert

The Nördlinger Ries Crater lacustrine basin (South-West Germany), formed by a meteorite impact in the Miocene (Langhian; ∼14.9 Ma), offers a well-established geological framework to understand the strengths and limitations of U-Pb LA-ICPMS (in situ Laser Ablation-Inductively Coupled Plasma Mass Spectrometry) geochronology as chronostratigraphic tool for lacustrine (and more broadly continental) carbonates. The post-impact deposits include siliciclastic basinal facies at the lake centre and carbonate facies at the lake margins, coevally deposited in a time window of >1.2 and <2 Ma. Depositional and diagenetic carbonate phases (micrites and calcite cements) were investigated from three marginal carbonate facies (Hainsfarth bioherm, Adlersberg bioherm and Wallerstein mound). Petrography combined with C and O stable isotope analyses indicate that most depositional and early diagenetic carbonates preserved pristine geochemical compositions and thus the U-Pb system should reflect the timing of original precipitation. In total, 22 U-Pb ages were obtained on 10 different carbonate phases from five samples. The reproducibility and accuracy of the U-Pb (LA-ICPMS) method were estimated to be down to 1.5% based on repeated analyses of a secondary standard (speleothem calcite ASH-15d) and propagated to the obtained ages. Micrites from the Hainsfarth, Adlersberg and Wallerstein facies yielded ages of 13.90 ± 0.25, 14.14 ± 0.20 and 14.33 ± 0.27 Ma, respectively, which overlap within uncertainties, and are consistent with the weighted average age of 14.30 ± 0.20 Ma obtained from all the preserved depositional and early diagenetic phases. Data indicate that sedimentation started shortly after the impact and persisted for >1.2 and <2 Ma, in agreement with previous constraints from literature, therefore validating the accuracy of the applied method. Later calcite cements were dated at 13.2 ± 1.1 (nw=2), 10.2 ± 2.7 and 9.51 ± 0.77 Ma, implying multiple post-depositional fluid events. This study demonstrates the great potential of the U-Pb method for chronostratigraphy in continental systems, where correlations between time-equivalent lateral facies are often out of reach. In Miocene deposits the method yields a time resolution within the 3rd order depositional sequences (0.5–5 Ma).



中文翻译:

里斯火山口湖相碳酸盐岩原位U-Pb 测年(中新世,德国西南部):对大陆碳酸盐年代地层学的影响

Nördlinger Ries Crater 湖泊盆地(德国西南部)由陨石撞击中新世(Langhian;~14.9 Ma)形成,提供了一个完善的地质框架来了解 U-Pb LA-ICPMS 的优势和局限性(就地激光烧蚀-电感耦合等离子体质谱)地质年代学作为湖泊(以及更广泛的大陆)碳酸盐岩的年代地层工具。撞击后沉积包括湖心的硅质碎屑盆地相和湖缘的碳酸盐岩相,共沉积时间窗>1.2 和<2 Ma。研究了三个边缘碳酸盐岩相(Hainsfarth bioherm、Adlersberg bioherm 和 Wallerstein 丘)的沉积和成岩碳酸盐相(泥晶石和方解石胶结物)。岩相学结合 C 和 O 稳定同位素分析表明,大多数沉积和早期成岩碳酸盐保留了原始地球化学成分,因此 U-Pb 系统应反映原始降水的时间。总共,从五个样品的 10 个不同碳酸盐相上获得了 22 个 U-Pb 年龄。U-Pb (LA-ICPMS) 方法的重现性和准确性根据二级标准(speleothem calcite ASH-15d)的重复分析估计低至 1.5%,并传播到获得的年龄。来自 Hainsfarth、Adlersberg 和 Wallerstein 相的泥晶岩的年龄分别为 13.90 ± 0.25、14.14 ± 0.20 和 14.33 ± 0.27 Ma,在不确定性范围内重叠,并且与从所有保存下来的所有保存的 Ma 中获得的加权平均年龄 14.30 ± 0.20 Ma 一致沉积和早期成岩阶段。数据表明,在撞击后不久开始沉积,并持续 >1.2 和 <2 Ma,与之前文献中的限制一致,因此验证了所应用方法的准确性。n=2)、10.2 ± 2.7 和 9.51 ± 0.77 Ma,这意味着多个沉积后流体事件。这项研究证明了 U-Pb 方法在大陆系统年代地层学方面的巨大潜力,在大陆系统中,时间等效的侧相之间的相关性通常是遥不可及的。在中新世沉积中,该方法在三阶沉积序列(0.5-5 Ma)内产生时间分辨率。

更新日期:2021-06-07
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