Single crystals of two pentanary cesium titanyl/titanate silicate oxyfluorides, Cs₃(TiO)Si₄O₁₀F and Cs₁₇(TiO)₁₂Ti₂Si₈O₄₀F, were grown from mixed cesium halide fluxes. Cs₃(TiO)Si₄O₁₀F crystallizes in the monoclinic space group P2₁/c with lattice parameters a = 6.9528(2) Å, b = 14.9471(4) Å, c = 12.7676(3) Å, and β = 91.2500(10)° and consists of a framework comprised of silicate sheets and (TiO)O₄F octahedra. Cs₁₇(TiO)₁₂Ti₂Si₈O₄₀F crystallizes in the tetragonal space group I4/m with lattice parameters a = 16.2181(4) Å and c = 13.3866(3) Å and is composed of two interpenetrating titanate silicate frameworks.

从混合的卤化铯助熔剂中生长出两种戊基铯钛基/钛酸硅酸盐氟氧化物，Cs ₃ (TiO)Si ₄ O ₁₀ F 和 Cs ₁₇ (TiO) ₁₂ Ti ₂ Si ₈ O ₄₀ F 的单晶。Cs ₃ (TiO)Si ₄ O ₁₀ F 在单斜空间群P 2 ₁ / c 中结晶，晶格参数a  = 6.9528(2) Å, b  = 14.9471(4) Å, c  = 12.7676(3) Å 和β = 91.2500(10)°，由硅酸盐片和 (TiO)O ₄ F 八面体组成的框架组成。Cs ₁₇ (TiO) ₁₂ Ti ₂ Si ₈ O ₄₀ F 在四方空间群I 4/ m 中结晶，晶格参数a  = 16.2181(4) Å 和c  = 13.3866(3) Å，由两个互穿的钛酸盐硅酸盐骨架组成.