当前位置: X-MOL 学术Trans. Indian Ceram. Soc. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Thickness Effect on Permeance of CO2/CH4 Gases in CA Coated PVDF Composite Membranes
Transactions of the Indian Ceramic Society ( IF 1.2 ) Pub Date : 2021-06-04 , DOI: 10.1080/0371750x.2021.1880969
Ayesha Raza 1 , Muhammad Fahad Yousaf 1 , Sarah Farrukh 1 , Arshad Hussain 1
Affiliation  

The aim of this work is to study the effect of membrane thickness with respect to gas permeance and tensile strength. The influence of membrane thickness on gas permeation has received little attention to date. Single layer flat sheet membrane with average thickness of 25 μm and dual layer composite membranes with variable thickness of skin layer were fabricated by coating CA/ PEG selective layer on the polyvinylidene fluoride porous support. Permeation experiments were performed with CO2 and CH4 which revealed that permeance of CO2 was pronounced compared to CH4. Highest permeance of 0.87 gas permeation unit (GPU) was obtained at 4 bar with 19.4 μm skin layer. Fourier transform infra-red spectroscopy was used to study the existence of different functional groups in the membranes. Strength of the membranes was analyzed using tensile testing machine. Scanning electron microscopy was used to study the surface structure and morphology. It was found that by reducing the membrane thickness, the permeance of CO2 and CH4 increased without compromising on membrane strength.



中文翻译:

厚度对 CA 涂层 PVDF 复合膜中 CO2/CH4 气体渗透率的影响

这项工作的目的是研究膜厚度对透气性和抗张强度的影响。迄今为止,膜厚度对气体渗透的影响很少受到关注。通过在聚偏二氟乙烯多孔载体上涂覆CA/PEG选择性层,制备了平均厚度为25μm的单层平板膜和表层厚度可变的双层复合膜。用 CO 2和 CH 4进行渗透实验,结果表明 CO 2 的渗透性比 CH 4 显着. 0.87 气体渗透单元 (GPU) 的最高渗透率在 4 bar 下获得,表层为 19.4 μm。傅里叶变换红外光谱用于研究膜中不同官能团的存在。使用拉伸试验机分析膜的强度。扫描电子显微镜用于研究表面结构和形态。发现通过降低膜厚度,CO 2和CH 4的渗透性增加而不影响膜强度。

更新日期:2021-06-29
down
wechat
bug