Abstract

The heterometallic complex (L¹)Ru(κ²-O₂CC₅H₄)Mn(CO)₃(O₂CC₅H₄)Mn(CO)₃) (I) (L¹ is the pivalate ligand) is synthesized by the reaction of the ruthenium(II) complex (L¹)Ru(κ²-O₂CCMe₃)(O₂CCMe₃) with cymantrenylcarboxylic acid (HO₂CC₅H₄)Mn(CO)₃. The consecutive reactions of nickel acetate with cymantrenenecarboxylic acid and diimine 1,4-di-tert-butyl-1,4-diazabutadiene-1,3 affords the complex (L²)Ni(κ²-O₂CC₅H₄Mn(CO)₃)₂ (II) (L² = ^tBu–N=CH–CH=N–^tBu). Complexes I and II are identified by the elemental and X-ray diffraction analyses data (СIF files CCDC nos. 2001354 (I) and 2001355 (II)).

中文翻译：

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钌和镍与花椒羧酸的配合物：合成和结构

摘要

异金属配合物 (L ¹ )Ru(κ ² -O ₂ CC ₅ H ₄ )Mn(CO) ₃ (O ₂ CC ₅ H ₄ )Mn(CO) ₃ ) ( I ) （L ¹是新戊酸盐配体）是由钌 (II) 配合物 (L ¹ )Ru(κ ² -O ₂ CCMe ₃ )(O ₂ CCMe ₃ ) 与氰基甲酸 (HO ₂ CC ₅ H ₄ )Mn(CO) ₃反应合成. 乙酸镍与cymantrenene羧酸和二亚胺1,4-二叔丁基-1,4-二氮杂丁二烯-1,3的连续反应得到配合物(L ² )Ni(κ ² -O ₂ CC ₅ H ₄ Mn( CO) ₃ ) ₂ ( II ) (L ² = ^t Bu–N=CH–CH=N– ^t Bu)。配合物I和II通过元素和 X 射线衍射分析数据（СIF 文件 CCDC 编号 2001354（I）和 2001355（II））确定。