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Characterization of (252Cf-ZrH2) Monte Carlo model for detection of nitrogen and chlorine by thermal neutron-capture PGNAA
Radiation Physics and Chemistry ( IF 2.9 ) Pub Date : 2021-06-03 , DOI: 10.1016/j.radphyschem.2021.109591
Nassreldeen A.A. Elsheikh

Monte Carlo calculations were conducted to explore the potentials of zirconium hydride (ZrH2) as possible alternative moderator for high density polyethylene (HDPE) and water (H2O) in a simple (100MBq) 252Cf-based Prompt Gamma Neutron Activation Analysis (PGNAA) assembly. The thickness of moderators was optimized against thermal neutron flux (ϕth) as well as the ratio of (thermal/fast) neutron flux (ϕthfast), calculated at the sample cavity. The capabilities of moderating 252Cf source neutrons and minimizing the γ-background due to 2525Cf fission γ-rays, 1H(nth,γ)2H γ-rays originates in the moderator as well as other (nth,γ) capture reactions from surroundings were investigated. The optimal selected moderator with sufficient (ϕth) at the sample cavity and minimum γ-contamination was selected as ZrH2 for use in a252Cf-PGNAA for detection of nitrogen and chlorine in bulk sample simulants of melamine (C3H6N6) and sodium chloride (NaCl). The prompt γ-rays spectra were analyzed to detect the 10.83 MeV and 6.11 MeV prompt γ-peaks released by 14N(nth,γ)15N and 35Cl(nth,γ)36Cl, respectively. The results showed that the (252Cf-ZrH2)-PGNAA model has positively identified nitrogen with net counts (1.25 × 105 n.cm−2.s−1) and Chlorine with net counts of (4.19 × 106 n.cm−2.s−1), achieving minimum detectable concentrations of about (350 ppm at 10.83 MeV) and (640 ppm at 6.11 MeV), respectively.



中文翻译:

( 252 Cf-ZrH 2 ) 用于通过热中子俘获 PGNAA 检测氮和氯的蒙特卡罗模型的表征

进行蒙特卡罗计算以探索氢化锆 (ZrH 2 ) 作为高密度聚乙烯 (HDPE) 和水 (H 2 O)可能的替代减速剂的潜力,在简单的 (100MBq) 252 Cf 基快速伽马中子活化分析中( PGNAA) 组装。慢化剂的厚度针对热中子通量 (ϕ th ) 以及(热/快)中子通量之比(ϕ th / ϕ fast)进行了优化,在样品腔处计算。缓和252 Cf 源中子和最小化2525 Cf 裂变 γ 射线引起的 γ 背景的能力,1 H(n th ,γ) 2H γ 射线起源于慢化剂以及来自周围环境的其他 (n th , γ) 俘获反应。在样品腔中具有足够 (ϕ th ) 和最小 γ 污染的最佳选择缓和剂被选为 ZrH 2用于252 Cf-PGNAA 中检测三聚氰胺 (C 3 H 6 N)散装样品模拟物中的氮和氯6 ) 和氯化钠 (NaCl)。分析瞬发γ射线谱,检测了14 N(n th ,γ) 15 N 和35 Cl(n th ,γ) 36释放的10.83 MeV和6.11 MeV瞬发γ峰。分别为 Cl。结果表明,( 252 Cf-ZrH 2 )-PGNAA 模型对氮的净计数为 (1.25 × 10 5 n.cm -2 .s -1 ) 和氯的净计数为 (4.19 × 10 6 n)。 cm -2 .s -1 ),分别达到约 (350 ppm 在 10.83 MeV) 和 (640 ppm 在 6.11 MeV) 的最小可检测浓度。

更新日期:2021-06-10
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