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Co-dispersion and co-deposition of clay/MoS2 and its application on epoxy nanocomposites
Iranian Polymer Journal ( IF 3.1 ) Pub Date : 2021-05-28 , DOI: 10.1007/s13726-021-00929-6
Han-Lin Xie , Wei Han , Xin Yan , Bao-Jian Ni , Bin Chen , He-Xin Zhang , Keun-Byoung Yoon

In recent years, polymer nanocomposites based on 2D materials have aroused widespread research interest. MoS2 exhibits many excellent properties due to its unique structure, such as mechanical properties, thermal stability, and fire resistance properties. It has great potential as a polymer reinforcement material and functional nanofiller. However, it is well known that the exfoliated MoS2 layers have a tendency to aggregate during mixing with polymers, which results in the polymer performance cannot be effectively improved. In this work, clay was introduced into molybdenum disulfide (MoS2) to improve the dispersion of exfoliated MoS2. After co-deposition, two different layered fillers co-stacked to form a novel clay/MoS2 composite. The presence of clay in the MoS2 slurry prevented aggregation of the individual clay and MoS2 layers. The resulting clay/MoS2 composite was further used as fillers to form epoxy/clay/MoS2 nanocomposites. The effects of clay, MoS2 and clay/MoS2 mixture on the properties of epoxy nanocomposites were investigated and compared. It was found that combining clay and MoS2 allows the enhancement of tensile strength and tensile modulus. Additionally, due to the well co-dispersion of clay and MoS2, the thermal stability and mechanical properties of epoxy/clay/MoS2 nanocomposites are higher than those of epoxy/clay and epoxy/MoS2 nanocomposites. Therefore, this work provides a facile way to produce high-performance epoxy nanocomposites.



中文翻译:

粘土/二硫化钼的共分散共沉积及其在环氧纳米复合材料中的应用

近年来,基于二维材料的聚合物纳米复合材料引起了广泛的研究兴趣。MoS 2由于其独特的结构而表现出许多优异的性能,例如机械性能、热稳定性和耐火性能。它作为聚合物增强材料和功能性纳米填料具有巨大的潜力。然而,众所周知,剥离的MoS 2层在与聚合物混合时有聚集的趋势,导致聚合物性能无法得到有效改善。在这项工作中,粘土被引入二硫化钼 (MoS 2 ) 以改善剥离的 MoS 2的分散。共沉积后,两种不同的层状填料共同堆叠形成新型粘土/MoS2复合。MoS 2浆料中粘土的存在防止了单独的粘土和MoS 2层的聚集。所得粘土/MoS 2复合材料进一步用作填料以形成环氧树脂/粘土/MoS 2纳米复合材料。研究并比较了粘土、MoS 2和粘土/MoS 2混合物对环氧纳米复合材料性能的影响。发现结合粘土和MoS 2可以提高拉伸强度和拉伸模量。此外,由于粘土和 MoS 2良好的共分散性,环氧树脂/粘土/MoS 2的热稳定性和机械性能纳米复合材料高于环氧树脂/粘土和环氧树脂/MoS 2纳米复合材料。因此,这项工作为生产高性能环氧纳米复合材料提供了一种简便的方法。

更新日期:2021-05-28
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