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Characterization of a green expanded DGT methodology for the in-situ detection of emerging endocrine disrupting chemicals in water systems
Sustainable Chemistry and Pharmacy ( IF 6 ) Pub Date : 2021-05-26 , DOI: 10.1016/j.scp.2021.100450
Helena Iuele , Nicholas Ling , Adam Hartland

Performances of sustainable and easy-to-make agarose (1.5%) – AC (1%) DGTs to monitor emerging EDCs were investigated. TGA, EDX showed agarose (1.5%) and agarose (1.5%) – AC (1%) biodegradable gels have constant water-carbon ratio along the two-dimensions ensuring consistent diffusive property and binding abilities. Gaussian simulations gave back lengths and widths of (12.32 Å; 5.11 Å), (12.32 Å; 6.77 Å), (10.18 Å; 4.36 Å), (10.23 Å; 4.83 Å) for E2, EE2, BPA and BPAF, respectively. FE-SEM characterization showed agarose (1.5%) has average pore number of 22 ± 5 μm2 with d.nm Ø 30 nm, while agarose (1.5%) – AC (1%) 13 ± 2 μm2 with d.nm Ø 45, ensuring free analytes diffusion. Effective diffusion coefficients at 25 °C were (3.97 ± 0.98 · 10-6 cm2 s-1), (3.18 ± 0.04 · 10-6 cm2 s-1), (3.09 ± 0.61 · 10−6 cm2 s-1), (3.55 ± 1.03 · 10-6 cm2 s-1) for E2, EE2, BPA and BPAF respectively. Kinetic studies showed agarose (1.5%) – AC (1%) uptakes, over the first 60 min, 97%, 95%, 98%, 98% of E2, EE2, BPA, BPAF, respectively with relative binding rates of 2.48, 3.55, 2.05, 1.20 ng cm-2 min-1. Agarose (1.5%) – AC (1%) DGT resulted suitable for EDCs in trace detection.



中文翻译:

绿色扩展的DGT方法的特性,用于就地检测水系统中新出现的内分泌干扰物

研究了可持续和易于制作的琼脂糖(1.5%)–交流(1%)DGT监测新兴EDC的性能。TGA,EDX显示琼脂糖(1.5%)和琼脂糖(1.5%)– AC(1%)可生物降解凝胶在二维方向上具有恒定的水碳比,从而确保一致的扩散性和结合能力。高斯模拟分别得出E2,EE2,BPA和BPAF的长度和宽度分别为(12.32Å; 5.11Å),(12.32Å; 6.77Å),(10.18Å; 4.36Å),(10.23Å; 4.83Å)。FE-SEM表征琼脂糖显示(1.5%)具有22±5微米的平均孔数2与d.nmØ30纳米,而琼脂糖(1.5%) - AC(1%)13±2微米2与d.nmØ 45,确保分析物自由扩散。25°C时的有效扩散系数为(3.97±0.98·10-6 cm 2 s -1),对于E2,EE2 (3.18±0.04·10-6 cm 2 s -1),(3.09±0.61·10 -6  cm 2  s -1),(3.55±1.03·10 -6  cm 2  s -1) ,BPA和BPAF。动力学研究表明,在开始的60分钟内,分别吸收了E2,EE2,BPA,BPAF的琼脂糖(1.5%)– AC(1%),97%,95%,98%,98%,相对结合率为2.48, 3.55、2.05、1.20 ng cm -2 min -1。琼脂糖(1.5%)– AC(1%)DGT适于痕量检测中的EDC。

更新日期:2021-05-26
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