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NH3 treatment of CeO2 nanorods catalyst for improving NH3-SCR of NO
Journal of the Energy Institute ( IF 5.7 ) Pub Date : 2021-05-23 , DOI: 10.1016/j.joei.2021.05.006
Yuhan Zhou , Shan Ren , Jie Yang , Weizao Liu , Zenghui Su , Zhichao Chen , Mingming Wang , Lin Chen

CeO2 nanorods (CeO2-NRs) catalyst was prepared and treated with ammonia (NH3) gas and the effect of NH3 treatment on CeO2 nanorods catalyst was also studied for improving NH3-SCR of NO. And the catalysts were tested for NH3-SCR of NO during 100–450 °C. The results showed that NH3 treatment could improve the De-NO efficiency of the catalyst, which increased evidently in the range of about 160–410 °C. XPS results revealed that NH3 treatment made CeO2-NRs catalyst produce more Ce3+ on its surface, and thereby produced more oxygen vacancies and further promoted SCR reaction. The XRD and H2-TPR characterization test results indicated that CeO2 catalyst with NH3 treatment could destroy its crystallinity and enhance the reducibility. In addition, the in situ DRIFTS results also exhibited more activity functional groups on the surface of N–CeO2-NRs catalyst than that of CeO2-NRs catalyst.



中文翻译:

CeO 2纳米棒催化剂的NH 3处理改善NO的NH 3 -SCR

制备了CeO 2纳米棒(CeO 2 -NRs)催化剂,并用氨气(NH 3)处理,并研究了NH 3处理对CeO 2纳米棒催化剂的影响,以提高NO的NH 3 -SCR。并在 100-450 °C 期间对催化剂的 NO 的NH 3 -SCR进行了测试。结果表明,NH 3处理可以提高催化剂的脱氮效率,在约160-410℃范围内有明显提高。XPS 结果表明NH 3处理使CeO 2 -NRs 催化剂产生更多的Ce 3+从而在其表面产生更多的氧空位并进一步促进 SCR 反应。XRD和H 2 -TPR表征测试结果表明,经过NH 3处理的CeO 2催化剂可以破坏其结晶度并提高还原性。此外,原位DRIFTS结果也显示出的N-的CeO的表面上更活性的官能团2个-NRS催化剂比的CeO 2 -NRS催化剂。

更新日期:2021-07-07
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