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A new supported Cu/Pd bimetallic nanoparticles composites prestoring reductant for nitrate removal: high reactivity and N 2 selectivity
Environmental Science and Pollution Research ( IF 5.8 ) Pub Date : 2021-05-15 , DOI: 10.1007/s11356-021-14372-w
Zhanhui Shen 1, 2 , Gege Peng 1 , Jialu Shi 1, 2 , Gao Ya 1
Affiliation  

Catalytic hydrogen reduction appears to be a promising strategy for nitrate removal. However, the danger and low utilization of H2 are the disadvantages of catalytic hydrogen reduction. Sodium borohydride (NaBH4), considered a potential candidate for hydrogen storage, has been investigated as an electron source for the catalytic reduction of contaminants. However, extensive use of NaBH4 makes commercialization costly and causes environmental pollution. In this study, we prepared supported Cu/Pd bimetallic nanoparticles that could prestore hydrogen. No additional reducing agent was required during the nitrate reduction process. The performance and mechanism of Cu/Pd bimetallic nanoparticles for nitrate reduction are discussed. Good performance was obtained with high reactivity (99.04% nitrate removal efficiency) and high selectivity for N2 (94.71%). The Cu/Pd bimetallic catalyst could be recovered by NaBH4 for 5 cycles. Moreover, a 97.49% nitrate removal efficiency was obtained for actual wastewater, indicating good prospects for nitrate reduction applications.



中文翻译:

一种新型负载型 Cu/Pd 双金属纳米粒子复合材料预储存还原剂用于去除硝酸盐:高反应性和 N 2 选择性

催化氢还原似乎是去除硝酸盐的有前途的策略。然而,H 2的危险性和低利用率是催化氢还原的缺点。硼氢化钠 (NaBH 4 ) 被认为是储氢的潜在候选者,已被研究作为催化还原污染物的电子源。然而,NaBH 4 的广泛使用使商业化成本高昂并造成环境污染。在这项研究中,我们制备了可以预储存氢的负载型 Cu/Pd 双金属纳米粒子。在硝酸盐还原过程中不需要额外的还原剂。讨论了Cu/Pd双金属纳米粒子还原硝酸盐的性能和机理。以高反应性(99.04% 硝酸盐去除效率)和高 N 2选择性(94.71%)获得了良好的性能。Cu/Pd双金属催化剂可以通过NaBH 4回收5个循环。此外,实际废水的硝酸盐去除效率为 97.49%,表明硝酸盐还原应用前景良好。

更新日期:2021-05-15
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