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Photocatalytic degradation of humic acid using a novel visible-light active α-Fe2O3/NiS2 composite photocatalyst
Journal of Environmental Chemical Engineering ( IF 7.7 ) Pub Date : 2021-05-15 , DOI: 10.1016/j.jece.2021.105682
Safia Syazana Mohtar , Farhana Aziz , Ahmad Rizam Mohamad Nor , Abdussamad Mukhtar Mohammed , Shakhawan Ahmad Mhamad , Juhana Jaafar , Norhaniza Yusof , Wan Norharyati Wan Salleh , Ahmad Fauzi Ismail

The effects of α-Fe2O3/NiS2 composite for the humic acid removal were systematically studied and compared with the synthesized α-Fe2O3 and NiS2. The obtained mesoporous composite has a stacked plate-like surface, active at a visible light region with a bandgap of 2.49 eV, and has a lower rate of recombination compared to the α-Fe2O3 but higher than the NiS2. The highest humic acid removal (93.7%) was achieved by the α-Fe2O3/NiS2 composite followed by the α-Fe2O3 (88.7%) and NiS2 (86.4%) at optimum conditions of 0.1 g L-1 catalyst loading, pH 5, and 30 mg L-1 initial humic acid concentration. The mineralization achieved 96.8% and the catalyst stable up to the fourth cycle. These encouraging results were due to the better adsorption capacity of the composite, being active in visible light, and quenching of the photoluminescence that led to effective separation of subsequent reduction in the rate of recombination of the charged carriers.



中文翻译:

使用一种新的可见光活性的α-Fe腐殖酸的光催化降解2 ö 3 / NIS 2复合光催化剂

α-Fe的影响2 ö 3 / NIS 2进行了系统研究复合的腐殖酸的脱除,并与合成的α-Fe相2 ö 3和NIS 2。将所获得的介孔复合体具有层叠板状的表面,在与2.49的带隙的可见光区域有源 电子伏特,且具有比的α-Fe重组较低速率2 ö 3但比的NiS更高2。最高腐殖酸的脱除(93.7%)是由达到的α-Fe 2 ö 3 / NIS 2复合,接着由的α-Fe 2 ö 3(88.7%)和NiS 2(86.4%)的最佳条件是:催化剂负载量为0.1  g  L -1,pH 5和最初的腐殖酸浓度为30  mg  L -1。矿化达到96.8%,并且催化剂稳定到第四个循环。这些令人鼓舞的结果是由于复合材料具有更好的吸附能力,在可见光中具有活性以及光致发光的猝灭,从而有效分离了带电载流子复合速率的后续降低。

更新日期:2021-05-15
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