Chinese solar greenhouse (CSG) is an energy-saving agricultural building which is used to grow vegetables in winter. The north wall of CSG plays an crucial role in concerning the production yield and quality during the winter months. To improve the thermal performance of north wall, different internal surface structures (ISS) with same materials were compared. Based on the field experiment and the proposed valuation, the dynamic heat storage-release characteristics of the north walls have been analyzed and discussed. The results showed that compared with the flat wall and the striped wall, the alveolate wall has better properties of heat storage and thermal insulation. Moreover, relative humidity in this type of greenhouse is more suitable for growing crops. The alveolate wall can improve indoor thermal environment and reduce the sensitivity to external environment. The obtained results can provide a basis for the scientific construction of the CSG north wall. It has significant potential for the area in high latitude, high altitude and long winter.