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Research progress on nanoporous carbons produced by the carbonization of metal organic frameworks
New Carbon Materials ( IF 5.7 ) Pub Date : 2021-05-10 , DOI: 10.1016/s1872-5805(21)60022-7
Qian Zhang , Chun-feng Xue , Jin-xin Wang , Rui-chao Huang , Xiao-gang Hao , Kai-xi Li

Nanoporous carbons (NPCs) are widely used in gas adsorption, catalysis and electrochemistry because of their high specific surface area, good thermal and chemical stability, etc. Although a lot of work has been done, there are still great challenges in the fabrication of NPCs. Metal organic frameworks (MOFs) with tailorable structures have the advantages of a regular and adjustable pore size, high porosity and high specific surface area, and have proved to be ideal precursors for the preparation of NPCs. To better grasp the state of the art in the preparation of NPCs, we review recent research progress on the fabrication of NPCs by the carbonization of MOFs, with a focus on the carbonization of different combinations of MOFs and guest precursors, both to tune the resulting pore sizes/textures and surface chemical structures/species and to improve the electrical conductivity and structural stability of the product in different applications.



中文翻译:

金属有机骨架碳化生成纳米孔碳的研究进展

纳米多孔碳(NPC)具有高的比表面积,良好的热稳定性和化学稳定性等优点,因此被广泛用于气体吸附,催化和电化学反应。尽管已经做了很多工作,但是在制造NPC方面仍然存在很大的挑战。 。具有可定制结构的金属有机骨架(MOF)具有规则且可调节的孔径,高孔隙率和高比表面积的优点,并且已被证明是制备NPC的理想前体。为了更好地掌握NPC制备的最新技术,我们回顾了通过MOF碳化制备NPC的最新研究进展,重点是MOF和客体前体的不同组合的碳化,

更新日期:2021-05-11
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