A kinetic model of polyunsaturated fatty acids (PUFAs) radical chain oxidation in micelles is presented, taking into account the diffusion of active intermediates between aqueous and organic phases, and its effect on the detailed mechanism of the process. The model made it possible to indirectly involve the structural changes of micelles and their kinetic characteristics by varying the actual values of the reactions rate constants. The modeling results are in good agreement with experimental data for the oxidation of methyl linoleate and linoleic acid.

中文翻译：

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胶束中多不饱和脂肪酸氧化的动力学模型。

介绍了胶束中多不饱和脂肪酸 (PUFA) 自由基链氧化的动力学模型，考虑到活性中间体在水相和有机相之间的扩散及其对过程详细机制的影响。该模型可以通过改变反应速率常数的实际值来间接涉及胶束的结构变化及其动力学特性。模拟结果与亚油酸甲酯和亚油酸氧化的实验数据非常吻合。