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CO and C 3 H 6 oxidation over La 0.9 Sr 0.1 CoO 3 catalysts: Influence of preparation solvent
Korean Journal of Chemical Engineering ( IF 2.7 ) Pub Date : 2021-05-06 , DOI: 10.1007/s11814-021-0781-9
Fei Yan , Ping Li , Xia Zhang

High surface area powders, La0.9Sr0.1CoO3 (LSCO), were prepared by a hard template method with a template of SBA-15. In the preparation process, the solvent was ethanol, the mixture of ethanol and water, and water, respectively. Characterizations were performed to understand the properties of the catalysts. When the solvent is a mixture of ethanol and water, the prepared LSCO has the most easily extracted surface adsorbed oxygen in the H2 atmosphere, exhibiting the best light-off performances for CO oxidation. However, the LSCO prepared in ethanol solvent has the best lattice oxygen mobility, resulting in the best light-off performance for C3H6 oxidation. Moreover, the LSCO prepared in ethanol also shows the best catalytic activity for both CO and C3H6 oxidation under the conditions of simulated diesel exhaust. Furthermore, Pd was impregnated on the LSCO, which was prepared by a sol-gel method and a hard template method, separately; the later one shows higher CO and C3H6 catalytic oxidation activity.



中文翻译:

La 0.9 Sr 0.1 CoO 3催化剂上的CO和C 3 H 6氧化:制备溶剂的影响

通过具有SBA-15模板的硬模板方法制备高表面积粉末La 0.9 Sr 0.1 CoO 3(LSCO)。在制备过程中,溶剂分别为乙醇,乙醇和水的混合物以及水。进行表征以了解催化剂的性质。当溶剂为乙醇和水的混合物时,制得的LSCO在H 2气氛中具有最容易提取的表面吸附氧,对CO氧化表现出最佳的起燃性能。然而,在乙醇溶剂中制备的LSCO具有最佳的晶格氧迁移率,因此对于C 3 H 6而言具有最佳的起燃性能。氧化。此外,在模拟柴油机排气条件下,乙醇中制备的LSCO对CO和C 3 H 6的氧化也显示出最佳的催化活性。另外,将Pd分别浸渍在通过溶胶-凝胶法和硬模板法制备的LSCO上。后者显示出较高的CO和C 3 H 6催化氧化活性。

更新日期:2021-05-07
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