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High-sensitivity based on Eu2+/Cr3+ co-doped BaAl12O19 phosphors for dual-mode optical thermometry
Journal of Luminescence ( IF 3.6 ) Pub Date : 2021-05-05 , DOI: 10.1016/j.jlumin.2021.118142
Yanting Zhu , Chenxia Li , Degang Deng , Hua Yu , Hao Li , Le Wang , Changyu Shen , Xufeng Jing , Shiqing Xu

A series of Eu2+/Cr3+ co-doped BaAl12O19 phosphor was synthesized by traditional high temperature solid stated method, and the temperature-sensitive characteristic of the phosphor was researched. Due to the temperature sensitivity of the fluorescence lifetime of Cr3+, the thermometry based on fluorescence lifetime can be realized. Furthermore, the emissions of Eu2+ ion and Cr3+ ion can be well separated, which shows the excellent signal recognition ability of this phosphor. The Eu2+/Cr3+ co-doped BaAl12O19 phosphor can be used for the thermometry based on fluorescence intensity ratio. A dual-mode optical thermometry is proposed and researched in the temperature range of 293–563 K by using the decay lifetime of Cr3+ emission and in the temperature range of 295–476 K by using the fluorescence intensity ratio of Eu2+ to Cr3+as temperature readout. The maximum values of relative sensitivity are 0.466% K−1 at 363 K and 0.259% K−1 at 476 K. The Eu2+/Cr3+ co-doped BaAl12O19 phosphor has excellent optical temperature characteristic, and its dual-mode thermometry characteristics provide convenience for the application of this material. This phosphor has potential application prospects in the field of optical thermometry.



中文翻译:

基于Eu 2+ / Cr 3+共掺杂的BaAl 12 O 19荧光粉的高灵敏度双模光学测温法

采用传统的高温固态法合成了一系列Eu 2+ / Cr 3+共掺杂BaAl 12 O 19荧光粉,研究了该荧光粉的温度敏感特性。由于Cr 3+荧光寿命的温度敏感性,因此可以实现基于荧光寿命的测温法。此外,可以很好地分离Eu 2+离子和Cr 3+离子的发射,这表明该荧光粉具有出色的信号识别能力。Eu 2+ / Cr 3+共掺杂BaAl 12 O 19荧光粉可根据荧光强度比用于测温。提出了一种双模光学测温法,并在293-563 K的温度范围内利用Cr 3+的发射衰变寿命进行了研究,并在295-476 K的温度范围内利用Eu 2+与荧光的强度比进行了研究。 Cr 3+作为温度读数。相对灵敏度的最大值是0.466%K -1,在363 K和0.259%K -1,在476 K的铕2+ / Cr的3+共掺杂的BaAl 12 ö 19磷光体具有出色的光学温度特性,其双模测温特性为该材料的应用提供了方便。该荧光粉在光学测温领域具有潜在的应用前景。

更新日期:2021-05-12
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