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A simplistic molecular agglomeration of carbon nitride for optimized photocatalytic performance
Surfaces and Interfaces ( IF 6.2 ) Pub Date : 2021-05-05 , DOI: 10.1016/j.surfin.2021.101166
Asif Hayat , T.A. Taha , Asma M. Alenad , Ikram Ullah , Syed Jawad Ali Shah , Ikram Uddin , Ijaz Ullah , Ashiq Hayat , Wasim Ullah Khan

Presently, we engineered carbon nitride CN by specialized molecular doping with cyanuric acid (CA) to improve the metallic, electronic and photocatalytic assets under solar energy. The integration of CA monomer in CN significantly improve the efficient charge mobility and give a robust casing due to carbon/sulfur ingredients. Findings confirm that the incorporation of CA in the heptazine framework of CN introduce a remarkable polarization in its conjugated state and consequently illustrate an obvious variability in its surface area, electronic structure, band distance and chemical composition. Moreover, this exceptional consistency significantly enhances the photocatalytic operation toward sustainability and therefore the superior UCN1:1 sample illustrated a momentous photocatalytic activity of H2 evolution as well of RhB pollutant photodegradation.



中文翻译:

氮化碳的简单分子团聚,可优化光催化性能

目前,我们通过专门的分子掺杂氰尿酸(CA)设计了氮化碳CN,以改善太阳能条件下的金属,电子和光催化资产。由于碳/硫成分,CA单体在CN中的整合显着改善了有效的电荷迁移率,并提供了坚固的外壳。研究结果证实,在CN的庚嗪骨架中掺入CA会在其共轭状态下引入明显的极化,因此说明其表面积,电子结构,能带距离和化学组成都有明显的变化。此外,这种出色的一致性显着增强了光催化操作的可持续性,因此,优级UCN 1:1样品说明了H 2的瞬时光催化活性。 以及RhB污染物的光降解。

更新日期:2021-05-14
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