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Improved mechanical performance and electrochemical corrosion of WC-Al2O3 composite in NaCl solution by adding the TiC additives
International Journal of Refractory Metals & Hard Materials ( IF 3.6 ) Pub Date : 2021-05-04 , DOI: 10.1016/j.ijrmhm.2021.105566
Bin Han , Shigen Zhu , Weiwei Dong , Yunfeng Bai , Hao Ding , Yilan Luo , Ping Di

In this study, 85-xWC-xTiC-15wt%Al2O3 (x = 0, 5, 10 and 20 wt%) composites were fabricated via hot pressing sintering technology. The influences of TiC additives on the mechanical performance and electrochemical behavior of WC-Al2O3 composite in NaCl solution were investigated. The mean size of WC grain showed a downward trend with the increase of TiC content. The relative density, hardness and fracture toughness of WC-based composites were improved by TiC additives. The maximum values of mechanical performance were obtained when TiC content was 10 wt%. Moreover, the research results indicated that TiC additives significantly increase the corrosion potential and decrease the corrosion current density in NaCl solution. When TiC content increased, the charge-change resistance (Rct) value presented an uptrend, and then decreased obviously when the TiC content reached 20 wt%. The XPS spectrum and SEM images proved that TiO2 passivation film was formed on the surface of WA15-10TiC composite. Therefore, it could be concluded that TiO2 passive film could inhibit further corrosion of the composite.



中文翻译:

通过添加TiC添加剂改善WC-Al 2 O 3复合材料在NaCl溶液中的机械性能和电化学腐蚀

在这项研究中,通过热压烧结技术制备了85-xWC-xTiC-15wt%Al 2 O 3(x = 0、5、10和20 wt%)复合材料。TiC添加剂对WC-Al 2 O 3的力学性能和电化学行为的影响研究了NaCl溶液中的复合材料。随着TiC含量的增加,WC晶粒的平均尺寸呈下降趋势。TiC添加剂可改善WC基复合材料的相对密度,硬度和断裂韧性。当TiC含量为10重量%时,获得了机械性能的最大值。此外,研究结果表明,TiC添加剂可显着提高NaCl溶液中的腐蚀电位并降低腐蚀电流密度。当TiC含量增加时,耐电荷变化性(R ct)值呈上升趋势,而当TiC含量达到20 wt%时,则明显下降。XPS光谱和SEM图像证明了TiO 2在WA15-10TiC复合材料的表面上形成钝化膜。因此,可以得出结论,TiO 2钝化膜可以抑制复合材料的进一步腐蚀。

更新日期:2021-05-23
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