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Some characteristics of solar cells with ZnO/ZnFe 2 O 4 /CdS/ZnS working anode
Optical and Quantum Electronics ( IF 3 ) Pub Date : 2021-05-03 , DOI: 10.1007/s11082-021-02922-y
N. A. Masmali , Z. Osman , A. K. Arof

In this work, solar cells with configuration FTO/ZnO/ZnFe2O4/CdS/ZnS/gel polymer electrolyte (GPE)/Pt/FTO have been fabricated. ZnFe2O4 was spin-coated on ZnO using 0.3, 0.4, 0.5, 0.6 and 0.7 M ZnFe2O4 in 2-methoxyethanol (C3H8O2) solution. Zinc ferrite is known to be stable and environmentally friendly. The phase structure and surface morphology of ZnFe2O4 have been identified by XRD and FESEM, respectively. Using the Williamson Hall equation, the crystallite size is 26, 28, 30, 57 and 63 nm for ZnFe2O4 derived from 0.3, 0.4, 0.5, 0.6 and 0.7 M solutions, respectively. The lattice strain is 0.19. 0.21, 0.23, 1.00 and 1.10% respectively. From UV–Vis spectroscopy the band gap is observed to decrease with ZnFe2O4-2-methoxyethanol (C3H8O2) concentrations. The cell fabricated with the 0.5 M ZnFe2O4 in 2-methoxyethanol (C3H8O2) solution, exhibits a fill factor (FF) of 28%, current density at zero voltage of 0.9 mA cm2 and electromotive force of 150 mV.



中文翻译:

ZnO / ZnFe 2 O 4 / CdS / ZnS工作阳极的太阳能电池的某些特性

在这项工作中,已经制造出具有FTO / ZnO / ZnFe 2 O 4 / CdS / ZnS /凝胶聚合物电解质(GPE)/ Pt / FTO构造的太阳能电池。使用0.3、0.4、0.5、0.6和0.7 M的ZnFe 2 O 4在2-甲氧基乙醇(C 3 H 8 O 2)溶液中将ZnFe 2 O 4旋涂在ZnO上。铁氧体锌被认为是稳定且环保的。分别通过XRD和FESEM鉴定了ZnFe 2 O 4的相结构和表面形态。使用Williamson Hall方程,ZnFe 2 O 4的微晶尺寸为26、28、30、57和63 nm分别来自0.3、0.4、0.5、0.6和0.7 M溶液。晶格应变为0.19。分别为0.21、0.23、1.00和1.10%。从紫外可见光谱观察到,带隙随着ZnFe 2 O 4 -2-甲氧基乙醇(C 3 H 8 O 2)的浓度而减小。用在2-甲氧基乙醇(C 3 H 8 O 2)中的0.5 M ZnFe 2 O 4制备的电池,其填充系数(FF)为28%,零电压下的电流密度为0.9 mA cm 2,电动势为150毫伏。

更新日期:2021-05-03
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