Integrated gasification processes have been presented as a potential solution to intensify performance by combining unit operations. Hence, this study was aimed to arrange desulfurization and hydrocarbon reforming stages in series for biomass gasification technology. Cu-Zn₂TiO₄ incorporated with CaSiO₃ filters (CuZT/pCF) were successfully synthesized by ball-milling for desulfurization step. The characterizations of the samples indicated CuZT grains were effectively placed into the host lattice. 20%CuZT loading remarkably enhanced the sulfur capture under reducing (48.1%) and oxidizing (39.8%) atmospheres by increasing affinity and preventing diffusion limitation. Besides, the impregnated filter with Ni/Al₂O₃ exhibited higher catalytic activity towards simultaneously CH₄ (73%) and C₆H₆ (85%) reforming, however the performances were decreased in the presence of H₂S. The hindered performance was accomplished by integrating the catalyst filter with the 20%CuZT/pCF adsorbent in two-stage removal process. The integrated process displayed superior reforming efficiencies for methane and benzene degradation in the H₂S atmosphere, which were 10 times higher for methane and 1.15 times higher for benzene than that of the single stage system. Meanwhile, the desulfurization rate of 71% was achieved at the end of 5 h. Herein, the innovative concept was found to be promising consecutive removal process for desulfurization and substantially hydrocarbon cracking.

集成气化工艺已被提出作为通过组合单元操作来增强性能的潜在解决方案。因此，本研究旨在为生物质气化技术安排一系列的脱硫和碳氢化合物重整阶段。通过球磨成功地合成了掺有CaSiO ₃滤料（CuZT / pCF）的Cu-Zn ₂ TiO ₄。样品的表征表明，CuZT晶粒有效地置于了主晶格中。通过增加亲和力和防止扩散限制，负载20％CuZT可以显着提高还原气氛（48.1％）和氧化气氛（39.8％）下的硫捕获率。此外，Ni / Al ₂ O ₃浸渍过滤器在同时进行CH ₄（73％）和C ₆ H ₆（85％）重整时显示出较高的催化活性，但是在H ₂ S存在下性能降低。通过将催化剂过滤器与20％的催化剂结合使用可降低性能两阶段去除过程中的CuZT / pCF吸附剂。集成工艺显示出H _2中甲烷和苯降解的卓越重整效率S气氛比单级系统的甲烷高10倍，苯高1.15倍。同时，在5 h结束时脱硫率达到71％。在本文中，发现了创新的概念是有希望的用于脱硫和基本上烃裂化的连续去除方法。