Abstract

A study of Herzberg kinetic states \({{c}^{1}}\Sigma _{{\text{u}}}^{ - }\), A'³Δ_u, \({{{\text{A}}}^{3}}\Sigma _{{\text{u}}}^{ + }\) is performed for molecular oxygen in the Earth’s middle atmosphere during the precipitation of high-energy protons and electrons into the atmosphere. It is shown for the first time that considering the transfer of energy from metastable molecular nitrogen N₂(\({{{\text{A}}}^{3}}\Sigma _{{\text{u}}}^{ + }\)) is important in the processes of exciting the vibrational levels of Herzberg O₂ states in the atmosphere. It is shown numerically that the contribution from processes of intermolecular energy transfer from metastable molecular nitrogen exceeds that of direct excitation of the Herzberg O₂ states by secondary electrons in the Earth’s middle atmosphere.

中文翻译：

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模拟带电粒子沉淀过程中地球大气层中分子氧的赫兹贝格态的振动种群

摘要

赫茨伯格运动状态的研究- \（{} \ {{C} ^ {1}} \西格玛_ {{\文本【U}}} ^），A” ³ Δ _ù， \（{{{\文本{ A}}} ^ {3}} \ Sigma _ {{{\ text {u}}} ^ {+} \）是在高能质子和电子向大气中沉淀过程中对地球中层大气中的分子氧执行的。首次显示了考虑从亚稳态分子氮N ₂（\（{{{\ text {A}}} ^ {3}} \ Sigma _ {{\ text {u}}} ^ {+} \））在激发Herzberg O ₂振动水平的过程中很重要大气中的状态。从数值上显示，亚稳分子氮分子间能量转移过程的贡献超过了地球中层大气中的二次电子对Herzberg O ₂态的直接激发。