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Pyrolysis of aquatic fern and macroalgae biomass into bio-oil: Comparison and optimization of operational parameters using response surface methodology
Journal of the Energy Institute ( IF 5.7 ) Pub Date : 2021-04-28 , DOI: 10.1016/j.joei.2021.04.010
Pei Wu , Xia Zhang , Jing Wang , Jia Yang , Xuanwei peng , Li Feng , Bo Zu , Yudong Xie , Mengke Li

Effect of temperature (300–500 °C), carrier gas flow rate (0.2–0.8 L min−1), and the heating rate (10–20 °C min−1) on the final bio-oil production from the Salvinia auriculata (SA) and Ulva lactuca (UL) was optimized using response surface methodology (RSM), established by a central composite design (CCD). The maximum bio-oil yield from UL was 34.8%, reached at 500 °C, 0.2 L min−1 nitrogen flow rate, and 10 °C min−1 heating rate. However, in the case of SA feedstock, the highest bio-oil yield was 32.3% at 400 °C, 0.5 L min−1 nitrogen flow rate, and 20 °C min−1 heating rate. Both bio-oil samples contained saturated and unsaturated hydrocarbons; but the average hydrocarbon chain length in UL bio-oil (C4–C16) was relatively shorter than bio-oil from SA (C6– C24). The bio-oil from A. filiculoides exhibited higher HHV values than that of UL derived bio-oil due to its relative large carbon and hydrogen concentration and small oxygen content. Although both the bio-oils showed different heating values, the UL biooil had more appropriate properties, i.e. lower viscosity and density.



中文翻译:

将水生蕨类植物和大型藻类生物质热解为生物油:使用响应面方法对运行参数进行比较和优化

温度(300–500°C),载气流速(0.2–0.8 L min -1)和加热速率(10–20°C min -1)对Salvinia auriculata最终生物油产量的影响(SA)和Ulva lactuca(UL)使用通过中央复合设计(CCD)建立的响应面方法(RSM)进行了优化。UL的最大生物油产率为34.8%,在500°C,0.2 L min -1氮气流速和10°C min -1加热速率下达到。但是,对于SA原料,在400°C,0.5 L min -1氮气流量和20°C min -1的情况下,最高的生物油产率为32.3%加热速率。两种生物油样品均含有饱和和不饱和烃。但是UL生物油中的平均烃链长度(C 4 –C 16)相对短于SA中的生物油(C 6 – C 24)。由于其相对较高的碳氢浓度和氧含量以及较低的氧含量,A。filiculoides的生物油具有比UL衍生的生物油更高的HHV值。尽管两种生物油均显示出不同的热值,但UL生物油具有更合适的性能,即较低的粘度和密度。

更新日期:2021-05-17
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