Treatment of Ru₃(CO)₁₂ with salicylaldimines [2-HOC₆H₄-CH =N–C₆H₄-4-R] [R = Me; Cl; Br; OMe; CF₃] in refluxing toluene gave three novel binuclear ruthenium carbonyl complexes {[µ-ƞ²-2-OC₆H₄-CH=N-C₆H₄-4-R)][µ-ƞ²-2-CH₂-OC₆H₄][µ-ƞ-NH-C₆H₄-4-R]}Ru₂(CO)₄ [R = Me (1), Cl (2), Br (3)] and three mononuclear carbonyl complexes [2-OC₆H₄-CH=N-C₆H₄-4-R][2-OC₆H₄-CH₂NH-C₆H₄-4-R]Ru(CO)₂ [R = Me (4), OMe (5), CF₃ (6)], respectively. The structures of 1–6 were fully characterized using IR and NMR spectroscopy, elemental analysis and single-crystal X-ray diffraction. These results suggest that the substituent group on the phenyl of salicylaldimine has a significant effect on the structure of the Ru complex.

水杨醛亚胺[2-HOC ₆ H ₄ -CH = N–C ₆ H ₄ -4-R]处理Ru ₃（CO）₁₂ [R = Me; 氯; 溴 OME; CF ₃ ]在回流甲苯，得到三种新型双核钌羰基络合物{[ μ - ƞ ² -2-OC ₆ H ^ ₄ -CH = NC ₆ H ^ ₄ -4-R）] [ μ - ƞ ² -2-CH ₂ - OC ₆ H ₄ ] [ µ - ƞ -NH-C ₆ H ₄ -4-R]} Ru₂（CO）₄ [R = Me（1），Cl（2），Br（3）]和三个单核羰基配合物[2-OC ₆ H ₄ -CH = NC ₆ H ₄ -4-R] [2- OC ₆ H ₄ -CH ₂ NH-C ₆ H ₄ -4-R] Ru（CO）₂ [R = Me（4），OMe（5），CF ₃（6）]。1 – 6的结构使用IR和NMR光谱，元素分析和单晶X射线衍射对它们进行了全面表征。这些结果表明，水杨醛亚胺的苯基上的取代基对Ru配合物的结构具有显着影响。