The rate constants for the reaction of OH radicals with six halogenated propenes—(Z)-CF₃CCl = CHCl (k₁), CHF₂CF=CF₂ (k₂), (E)-CF₃CH=CHF (k₃), (Z)-CF₃CH=CHF (k₄), CH₃CF=CH₂ (k₅), and CH₂FCH=CH₂ (k₆)—were measured over 250–430 K using the absolute rate method. The Arrhenius expressions for the rate constants were determined as k₁ = (9.30 ± 0.54) × 10⁻¹³ exp [−(180 ± 20)/T], k₂ = (1.43 ± 0.04) × 10⁻¹² exp [(490 ± 10)/T], k₃ = (4.86 ± 0.13) × 10⁻¹³ (T/298)^0.727 exp [(110 ± 10)/T], k₄ = (4.55 ± 0.12) × 10⁻¹³ (T/298)^0.367 exp [(350 ± 10)/T], k₅ = (3.22 ± 0.20) × 10⁻¹² exp [(490 ± 20)/T], and k₆ = (2.87 ± 0.19) × 10⁻¹² exp [(440 ± 20)/T] cm³ molecule⁻¹ s⁻¹. Infrared absorption spectra of the halogenated propenes were measured at room temperature. The atmospheric lifetimes, global warming potentials of the halogenated propenes, and ozone depletion potential of (Z)-CF₃CCl = CHCl were estimated. The correlation between the reactivity and structure of 44 halogenated alkenes, including the six halogenated propenes, was investigated.

OH自由基与六个卤化丙烯-（Z）-CF ₃ CCl = CHCl（k ₁），CHF ₂ CF = CF ₂（k ₂），（E）-CF ₃ CH = CHF（k ₃），（Z）-CF ₃ CH = CHF（k ₄），CH ₃ CF = CH ₂（k ₅）和CH ₂ FCH = CH ₂（k ₆）—使用绝对速率方法在250–430 K范围内进行了测量。速率常数的Arrhenius表达式确定为k ₁ =（9.30±0.54）×10 ^-13 exp [-（180±20）/ T ]，k ₂ =（1.43±0.04）×10 ^-12 exp [（490 ±10）/ T ]，k ₃ =（4.86±0.13）×10 ^-13（T / 298）^0.727 exp [（110±10）/ T ]，k ₄ =（4.55±0.12）×10 ^-13（T / 298）^0.367 exp [（350±10）/ T ]，k ₅=（3.22±0.20）×10 ^-12 exp [（490±20）/ T ]，k ₆ =（2.87±0.19）×10 ^-12 exp [（440±20）/ T ] cm ³分子^-1  s ^-1。在室温下测量卤代丙烯的红外吸收光谱。估算了大气寿命，卤化丙烯的全球变暖潜势以及（Z）-CF ₃ CCl = CHCl的臭氧耗竭势。研究了包括六个卤代丙烯在内的44种卤代烯烃的反应性与结构之间的相关性。