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Using the elastic properties of zircon-garnet host-inclusion pairs for thermobarometry of the ultrahigh-pressure Dora-Maira whiteschists: problems and perspectives
Contributions to Mineralogy and Petrology ( IF 3.5 ) Pub Date : 2021-04-22 , DOI: 10.1007/s00410-021-01793-6
Nicola Campomenosi , Marco Scambelluri , Ross J. Angel , Joerg Hermann , Mattia L. Mazzucchelli , Boriana Mihailova , Francesca Piccoli , Matteo Alvaro

The ultrahigh-pressure (UHP) whiteschists of the Brossasco-Isasca unit (Dora-Maira Massif, Western Alps) provide a natural laboratory in which to compare results from classical pressure (P)–temperature (T) determinations through thermodynamic modelling with the emerging field of elastic thermobarometry. Phase equilibria and chemical composition of three garnet megablasts coupled with Zr-in-rutile thermometry of inclusions constrain garnet growth within a narrow PT range at 3–3.5 GPa and 675–720 °C. On the other hand, the zircon-in-garnet host-inclusion system combined with Zr-in-rutile thermometry would suggest inclusion entrapment conditions below 1.5 GPa and 650 °C that are inconsistent with the thermodynamic modelling and the occurrence of coesite as inclusion in the garnet rims. The observed distribution of inclusion pressures cannot be explained by either zircon metamictization, or by the presence of fluids in the inclusions. Comparison of the measured inclusion strains with numerical simulations shows that post-entrapment plastic relaxation of garnet from metamorphic peak conditions down to 0.5 GPa and 600–650 °C, on the retrograde path, best explains the measured inclusion pressures and their disagreement with the results of phase equilibria modelling. This study suggests that the zircon-garnet couple is more reliable at relatively low temperatures (< 600 °C), where entrapment conditions are well preserved but chemical equilibration might be sluggish. On the other hand, thermodynamic modelling appears to be better suited for higher temperatures where rock-scale equilibrium can be achieved more easily but the local plasticity of the host-inclusion system might prevent the preservation of the signal of peak metamorphic conditions in the stress state of inclusions. Currently, we cannot define a precise threshold temperature for resetting of inclusion pressures. However, the application of both chemical and elastic thermobarometry allows a more detailed interpretation of metamorphic PT paths.



中文翻译:

使用锆石-石榴石主体-内含物对的弹性特性进行超高压多拉-迈拉(Dora-Maira)Whiteschists的热压法:问题和观点

Brossasco-Isasca装置(西阿尔卑斯山Dora-Maira Massif)的超高压(UHP)白化主义者提供了一个自然实验室,可以在其中比较通过热力学建模将新兴的经典压力(P)-温度(T)确定的结果与新兴的弹性热压计领域。三颗石榴石成核细胞的相平衡和化学成分,再加上Zr的金红石内含物温度法,将石榴石的生长限制在狭窄的PT范围内温度范围为3–3.5 GPa和675–720°C。另一方面,石榴石中锆石-主体-夹杂物系统与金红石-锆金相测温法相结合,表明夹杂物的夹带条件低于1.5 GPa和650°C,这与热力学模型和在包裹体中发生堇青石是不相符的。石榴石轮辋。锆石的成矿作用或夹杂物中是否存在流体都不能解释观察到的夹杂物压力分布。通过数值模拟对所测夹杂物进行比较,结果表明,在逆行路径上,从低至0.5 GPa和600–650°C的变质峰条件,石榴石的包埋后塑性弛豫,可以最好地解释所测夹杂物压力及其与结果的不同之处。相平衡建模。这项研究表明,锆石-石榴石对在相对较低的温度(<600°C)下更可靠,在该温度下可以很好地保留包封条件,但化学平衡可能会变慢。另一方面,热力学模型似乎更适合于较高的温度,在该温度下更容易实现岩石尺度的平衡,但是主体包裹体系统的局部可塑性可能会阻止应力状态下的峰值变质条件信号的保存。夹杂物。目前,我们无法定义用于重置夹杂物压力的精确阈值温度。然而,化学和弹性热压法的应用都可以对变质进行更详细的解释。捕集条件得到很好保存但化学平衡可能缓慢的地方。另一方面,热力学模型似乎更适合于较高的温度,在该温度下更容易实现岩石尺度的平衡,但是主体包裹体系统的局部可塑性可能会阻止应力状态下的峰值变质条件信号的保存。夹杂物。目前,我们无法定义用于重置夹杂物压力的精确阈值温度。然而,化学和弹性热压法的应用都可以对变质进行更详细的解释。捕集条件得到很好保存但化学平衡可能缓慢的地方。另一方面,热力学模型似乎更适合于较高的温度,在该温度下更容易实现岩石尺度的平衡,但是主体包裹体系统的局部可塑性可能会阻止应力状态下的峰值变质条件信号的保存。夹杂物。目前,我们无法定义用于重置夹杂物压力的精确阈值温度。然而,化学和弹性热压法的应用都可以对变质进行更详细的解释。热力学模型似乎更适合于更高的温度,在更高的温度下更容易实现岩石尺度平衡,但是主体-包裹体系统的局部可塑性可能会阻止在包裹体的应力状态下保留峰值变质条件信号。目前,我们无法定义用于重置夹杂物压力的精确阈值温度。然而,化学和弹性热压法的应用都可以对变质进行更详细的解释。热力学模型似乎更适合于更高的温度,在更高的温度下更容易实现岩石尺度平衡,但是主体-包裹体系统的局部可塑性可能会阻止在包裹体的应力状态下保留峰值变质条件信号。目前,我们无法定义用于重置夹杂物压力的精确阈值温度。然而,化学和弹性热压法的应用都可以对变质进行更详细的解释。PT路径。

更新日期:2021-04-22
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