当前位置: X-MOL 学术J. Lumin. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Exploiting intervalence charge-transfer engineering to finely control (Ba, Sr)TiO3:Pr3+ luminescence thermometers
Journal of Luminescence ( IF 3.6 ) Pub Date : 2021-04-21 , DOI: 10.1016/j.jlumin.2021.118103
Wei Tang , Chuandong Zuo , Yingkui Li , Chaoyang Ma , Xuanyi Yuan , Zicheng Wen , Yongge Cao

Most recently, it has been demonstrated that the use of 3P03H4/1D2-3H4 intensity ratio of Pr3+ transitions is potentially beneficial to luminescence thermometry. In this study, a study is conducted of (Ba1-xSrx)TiO3:0.5%:Pr3+ phosphors following Sr2+ concentrations range (x = 0–0.5) in terms of luminescence thermometry. Besides, an investigation is carried out into thermoluminescence properties, based on which a discussion is conducted about the potential mechanisms behind the experimental results. It is discovered from Pr3+-Ti4+ that the highly efficient thermometric characteristics contribute significantly to the intervalence charge transfer state. Furthermore, through intervalence charge-transfer engineering, the effective management of their thermometric properties is made achievable due to the Ba2+ substitution by Sr2+, which makes the range of the highest relative sensitivity controllable. In the meantime, the maximal relative temperature sensitivity of Pr3+-doped BaTiO3 reaches up to 2.77% K−1 at 371 K as measured. This is expected to shed light on the design of one optical thermometer calibrated itself, exhibiting great performance.



中文翻译:

利用间隔电荷转移工程来精细控制(Ba,Sr)TiO 3:Pr 3+发光温度计

最近,已经证实的是,使用3 P 0 - 3 ħ 4 / 1 d 2 - 3 ħ 4的Pr强度比3+的过渡是发光测温潜在有益的。在这项研究中,对(Ba 1-x Sr x)TiO 3:0.5%:Pr 3+荧光粉跟随Sr 2+进行了研究发光测温法的浓度范围(x = 0–0.5)。此外,对热致发光性质进行了研究,在此基础上对实验结果背后的潜在机理进行了讨论。从Pr 3+ -Ti 4+发现,高效的测温特性显着地影响了间隔电荷转移状态。此外,通过间隔电荷转移工程,由于Ba 2+被Sr 2+取代,可以实现对它们的测温特性的有效管理,这使得最高相对灵敏度的范围是可控的。同时,Pr 3+的最大相对温度敏感性所测量,掺杂的BaTiO 3在371 K下达到2.77%K -1。预期这将为一个自行校准的光学温度计的设计提供启发,并表现出出色的性能。

更新日期:2021-04-26
down
wechat
bug