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Optical properties of Nd3+ ions doped GdTaO4 for pressure and temperature sensing
Journal of Rare Earths ( IF 4.9 ) Pub Date : 2021-04-20 , DOI: 10.1016/j.jre.2021.04.003
Pengyu Zhou , Qingli Zhang , Fang Peng , Baoquan Sun , Xiuming Dou , Bao Liu , Dandan Han , Yongzhou Xue , Kun Ding

Pressure- and temperature-dependent luminescence properties of 3F3/2 → 4I9/2 transition of Nd3+:GdTaO4 were studied for potential applications in optical sensing. Two isolated emission lines corresponding to 3F3/2 (R2, 1) → 4I9/2 (Z5) transitions, located at 920 and 927 nm under ambient condition, are very sensitive to pressure with coefficients of −15.6 and −14.5 cm−1/GPa determined in a pressure range up to about 9 GPa. The luminescence intensity ratio between the two emission lines exhibits a large dependence with temperature in a range from 80 to 620 K, the corresponding temperature sensitivity at room temperature is similar to that of Nd3+:YAG. These advantages, together with the other observed features of high stable position relationship under pressure and low thermal shifts for the two emission lines indicate that Nd3+:GdTaO4 is a promising candidate to be used as pressure and temperature sensors in the near-infrared spectral range.



中文翻译:

用于压力和温度传感的 Nd3+ 离子掺杂 GdTaO4 的光学特性

研究了 Nd 3+ :GdTaO 4的3 F 3/2  →  4 I 9/2跃迁的压力和温度依赖性发光特性,以用于光学传感中的潜在应用。对应于3 F 3/2 (R 2, 1 ) → 4 I 9/2 (Z 5 ) 跃迁的两条隔离发射线,在环境条件下位于 920 和 927 nm,对压力非常敏感,系数为 -15.6 和-14.5 厘米-1/GPa 在高达约 9 GPa 的压力范围内确定。两条发射线之间的发光强度比在80~620 K范围内随温度的变化很大,室温下相应的温度敏感性与Nd 3+ :YAG相似。这些优势,以及在压力下观察到的高稳定位置关系和两条发射线的低热位移的其他特征表明,Nd 3+ :GdTaO 4是一种很有前途的候选者,可用作近红外中的压力和温度传感器光谱范围。

更新日期:2021-04-20
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