Abstract

Such Nikolay Nikolayevich Semyonov’s discoveries as branching of reaction chains and features of chain combustion mechanism at low pressures (in the absence of self-heating) were shown to play a decisive role also at high pressures, in flame propagation, and in explosion and detonation. A physicochemical mechanism was revealed that ensures high rates and accelerations of reactions, consumption of reactants within hundred-thousandths of a second, and transition of combustion to explosion and detonation. Previously unexplainable laws of all the combustion modes were explained. Chemical methods based on the laws of chain reactions were developed to control combustion, explosion, and detonation.

中文翻译：

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链反应定律在气体燃烧，爆炸和爆炸过程中的决定性作用

摘要

尼古拉·尼古拉耶维奇·塞梅诺诺夫（Nikolay Nikolayevich Semyonov）的发现，即反应链的分支和低压（在没有自热的情况下）链燃烧机理的特征，在高压，火焰传播，爆炸和爆炸中也起着决定性的作用。揭示了一种物理化学机制，可以确保高速率和加速反应，在十万分之一秒内消耗反应物，以及燃烧过渡到爆炸和爆炸。以前解释了所有燃烧模式的无法解释的规律。开发了基于链反应定律的化学方法来控制燃烧，爆炸和爆炸。