Abstract

A retrospective review based on the authors’ work is devoted to homogeneous catalytic systems based on aqueous solutions of Mo–V–P heteropolyacids (HPA-x, x is the number of vanadium atoms). These catalytic systems were first proposed for oxidative reactions at Boreskov Institute of Catalysis. The properties of HPA-x solutions, methods for their synthesis, promising processes occurring in their presence, problems related to the use of these solutions, and ways of solving these problems are considered. Prospects for the creation of industrial processes based on modified high-vanadium HPA-x solutions of non-Keggin compositions are shown.

中文翻译：

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基于钼钒钒磷酸杂多酸高钒溶液的催化剂：成就，挑战和前景

摘要

基于作者工作的回顾性研究致力于基于Mo-V-P杂多酸水溶液（HPA- x，x为钒原子数）的均相催化体系。这些催化体系最初是在Boreskov催化研究所提出用于氧化反应的。HPA- x解决方案的属性，其合成方法，存在时可能出现的有前景的过程，与这些解决方案的使用有关的问题以及解决这些问题的方法均应加以考虑。显示了基于非Keggin组合物的改性高钒HPA- x溶液创建工业流程的前景。