Catalysis Communications ( IF 3.7 ) Pub Date : 2021-04-14 , DOI: 10.1016/j.catcom.2021.106315 Liwei Feng , Bingdong Li , Yuqi Xiao , Lijuan Li , Yuqian Zhang , Qiannan Zhao , Guifu Zuo , Xianguang Meng , Vellaisamy A.L. Roy
In this work, an Au modified Bi2O3-TiO2 (Au/Bi2O3-TiO2) hybrid is developed as a simple and effective photocatalyst for the production of H2O2. The modification of Bi2O3 improves the charge separation of photocatalyst and significantly enhances the photocatalytic activity of Au/TiO2 for H2O2 production. In-situ electron spin resonance studies shows stepwise single-electron oxygen reduction reaction (ORR) on the Au/Bi2O3-TiO2 photocatalyst for the production of H2O2. This work demonstrates the importance of heterojunction structure photocatalyst for improved performance of TiO2 in order to produce concentrated H2O2.
中文翻译:
Au修饰的Bi 2 O 3 -TiO 2杂化物光催化合成过氧化氢
在这项工作中,Au改性的Bi 2 O 3 -TiO 2(Au / Bi 2 O 3 -TiO 2)杂化物被开发为一种简单有效的用于生产H 2 O 2的光催化剂。Bi 2 O 3的改性改善了光催化剂的电荷分离,并显着增强了Au / TiO 2对H 2 O 2的生产的光催化活性。原位电子自旋共振研究表明Au / Bi 2 O 3 -TiO 2上的逐步单电子氧还原反应(ORR)用于生产H 2 O 2的光催化剂。这项工作证明了异质结结构光催化剂对于提高TiO 2性能以生产浓H 2 O 2的重要性。