Abstract

For better visualization of solvent effects on spin-spin coupling constants (SSCCs) we have investigated some organomercury compounds, which have large solvent induced changes on one-bond C-Hg SSCCs. Extra large solvent effects (up to 20% of SSCC value) have been observed, which allow to more carefully examine the peculiarities of SSCC’s solvent and electric field dependencies in various media.

中文翻译：

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溶剂对有机汞化合物中自旋-自旋偶合常数的影响

摘要

为了更好地观察溶剂对自旋-旋转偶合常数（SSCC）的影响，我们研究了一些有机汞化合物，这些化合物在单键C-Hg SSCC上具有较大的溶剂诱导变化。已经观察到超大的溶剂效应（高达SSCC值的20％），可以更仔细地检查SSCC溶剂的特性和在各种介质中的电场依赖性。