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Synthesis and Properties of Fused Triad Donors Composed of Two 1,3-Dithiole[5]radialenes and Extended Tetrathiafulvalene
Heterocycles ( IF 0.6 ) Pub Date : 2021-04-01 , DOI: 10.3987/com-21-14428
Yohji Misaki , Kohei Kagawa , Takayuki Higashi , Aya Yoshimura

Synthesis of fused triad donors composed of two 1,3-dithiole[5]radialenes and one vinyl-extended or thiophene-inserted teterathiafulvalene (5, 6) have been successfully synthesized. Both donors exhibited simultaneous eight-electron oxidation attributed to simultaneous oxidation of two extended 1,3-dithiole[5]radialene units.

中文翻译:

由两个1,3-二硫代[5] Radalenes和扩展的四硫富瓦烯组成的熔融三元体供体的合成和性能

稠合的三单元组供体的合成由两个1,3-二硫[5]轴烯和一种乙烯基延伸或噻吩插入teterathiafulvalene(的5 6 )已经被成功地合成。两个供体均表现出同时的八电子氧化,这归因于两个延伸的1,3-二硫代[5]]基单元的同时氧化。
更新日期:2021-05-27
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