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Petrogenesis of the late Mesozoic Bashan complex in the Lower Yangtze River Belt, eastern China: Implications for the definition and significance of A-type granite
Lithos ( IF 3.5 ) Pub Date : 2021-03-31 , DOI: 10.1016/j.lithos.2021.106144
Chao Yang , Jun Yan , Sinuo Wang , Shiming Song , Dingyuan Zhang , Jianmin Liu

Many late Mesozoic granites within the Lower Yangtze River Belt (LYRB), eastern China, are defined as A-types based on their geochemical characteristics, although their petrogenesis is unclear. We present an integrated study combining geochronology, whole-rock geochemistry, Sr, Nd, Pb and zircon Hf isotopes and mineral chemistry for a lithologically-diverse suite of A-type granitoids at Bashan. The Bashan complex in the Chizhou area is composed of quartz monzonite, quartz syenite, syenogranite and alkali-feldspar granite. Zircon Usingle bondPb geochronology indicates that these intrusive rocks formed at 126–123 Ma. The quartz monzonites have intermediate SiO2 (60.5–63.1 wt%) and high Na2O + K2O (8.66–9.83 wt%) contents, arc-like trace element compositions, enriched whole-rock Sr, Nd and zircon Hf isotopes ((87Sr/86Sr)i = 0.7082–0.7091; εNd(t) = −6.9 to −7.1; εHf(t) = −5.3 to −8.2) and high radiogenic Pb isotopes (206Pb/204Pb(t) = 18.581–18.792). They are inferred to have been derived from partial melting of an enriched lithospheric mantle source, followed by fractional crystallisation and limited crustal contamination. The quartz syenites show high SiO2 (65.9–69.8 wt%) and Na2O + K2O (11.3–12.3 wt%) contents, low MgO (0.14–0.23 wt%) contents, high 104 * Ga/Al (2.34–3.61) values, arc-like trace element compositions, and whole-rock Nd and Pb and zircon Hf isotopic compositions (εNd(t) = −6.8 to −7.0; εHf(t) = −7.3 to −12.3; 206Pb/204Pb(t) = 18.559–18.970) similar to the quartz monzonite, suggesting that they were derived through fractional crystallisation of the quartz monzonite, with some crustal assimilation. The quartz monzonite has higher Ti-in-zircon temperatures (TTi-in-Zrn = 696–832 °C) and lower zircon saturation temperatures (TZr = 772–818 °C) and oxygen fugacities (ΔFMQ = +1.8 to +2.8) than the quartz syenite (TTi-in-Zrn = 623–805 °C; TZr = 856–909 °C; ΔFMQ = +3.5 to +4.8), indicating that the zircons from the quartz syenite crystallised at lower temperatures, and that the oxygen fugacity significantly elevated as the magmatic temperature decreases. The syenogranites display high SiO2 (74.6–75.5 wt%) contents, high TTi-in-Zrn (671–871 °C), TZr (799–822 °C), and low oxygen fugacities (ΔFMQ = +0.9 to +3.7), and thus did not evolve from the quartz syenite. They show high 104 * Ga/Al values (2.67–2.95), low MgO (0.1–0.17 wt%) contents and (La/Yb)N (7.60–10.19) ratios, pronounced negative Eu anomalies (Eu/Eu* = 0.28–0.38) and enriched Sr, Nd and zircon Hf isotopic compositions (εNd(t) = −7.2 to −7.5; εHf(t) = −5.1 to −14.0), indicating that they were derived from fluid-absent partial melting of Neoproterozoic calc-alkaline igneous rocks under low-pressure–high-temperature conditions. The alkali-feldspar granites are characterised by high SiO2 (76.5–78.0 wt%) and Na2O + K2O (8.34–9.02 wt%) contents, but low MgO (0.03–0.08 wt%) contents. They show less enriched Nd isotopes (εNd(t) = −5.7), a wide range of zircon εHf(t) values (−1.9 to −11.2) and high oxygen fugacities (ΔFMQ = +2.9 to +4.3). They were produced by mixing of highly-fractionated alkaline basaltic magmas and melts derived from partial melting of Mesoproterozoic crust. The inferred petrogenesis of the Bashan complex magmatic rocks suggests that the A-type granites within the LYRB have multiple magmatic sources and crystallised under a wide range of temperatures, water contents and oxygen fugacities. During the Mesozoic, subduction and rollback of the Palaeo-Pacific slab induced crustal extension and intense crust–mantle interaction, which played a dominant role in the formation of the A-type granites within the LYRB.

更新日期:2021-04-02
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