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Synthesis of a high surface area and highly dispersed Cu-O-Si complex oxide used for the low-temperature hydrogenation of dimethyl oxalate to ethylene glycol
Catalysis Communications ( IF 3.7 ) Pub Date : 2021-03-26 , DOI: 10.1016/j.catcom.2021.106310
Yu Zhao , Xian Kan , Hongfei Yun , Dongliang Wang , Ning Li , Guixian Li , Jianyi Shen

A highly dispersed Cu-O-Si composite oxide framework catalyst with high surface area (619 m2/g) and very small particle size (~3 nm) has been synthesized using an improved precipitation method, which showed high catalytic activity toward the hydrogenation of dimethyl oxalate (DMO) (99.9% conversion of DMO and 96.7% selectivity for ethylene glycol) even at low temperature (175 °C). In addition, its chemical stability was significantly enhanced due to the formation of a Cu-O-Si composite structure and the low reaction temperature, and the catalyst did not show any significant inactivation during the stability test over 140 h.



中文翻译:

高表面积高分散Cu-O-Si复合氧化物的合成,用于草酸二甲酯的低温加氢成乙二醇

使用改进的沉淀法合成了具有高表面积(619 m 2 / g)和非常小的粒径(〜3 nm)的高度分散的Cu-O-Si复合氧化物骨架催化剂,该催化剂对氢化反应显示出很高的催化活性。草酸二甲酯(DMO)的转化率(DMO的转化率为99.9%,对乙二醇的选择性为96.7%),即使在低温(175°C)下也是如此。此外,由于形成了Cu-O-Si复合结构和较低的反应温度,其化学稳定性得到了显着提高,并且在140 h的稳定性测试过程中,该催化剂没有出现任何明显的失活现象。

更新日期:2021-04-02
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