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Source of 226 Ra in Ramsar spring water, Iran: implication of water–rock interaction and stable isotopes
Environmental Earth Sciences ( IF 2.8 ) Pub Date : 2021-03-27 , DOI: 10.1007/s12665-021-09527-4
Farideh Amini Birami , Farid Moore , Mohammad Reza Kardan , Behnam Keshavarzi , Mehdi Zarei , Peter S. Hooda

This study was carried out primarily to understand the hydrogeochemical processes controlling the 226Ra anomalies in Ramsar area. Analyses revealed two types of water: (1) non-thermal Ca–HCO3 type and (2) thermal Na–Cl type, mainly of meteoric and hydrothermal origin, respectively. Non-thermal springs have higher concentrations of U due to silicate weathering. Thermal springs are characterized by high concentrations of 226Ra, As, Fe, Li, Cs, Rb, Sr, Ba, B, Br, F, NO3, PO43− and SiO2 resulting from high-temperature water–rossck interaction and mixing with hydrothermal fluids. Thermal springs are manifestations of an old hydrothermal system with subsurface reservoir temperatures varying between 83 and 100 °C. Radium activity is negatively correlated with pH and positively correlated with TDS, Cl, Ba, and Ca, reflecting competitive ion effects of alkaline-earth metals, complexing with Cl, and co-precipitation with barite and calcite. These processes are thought to be the dominant factors in controlling 226Ra mobility in spring water.



中文翻译:

伊朗拉姆萨尔泉水中226 Ra的来源:水-岩相互作用和稳定同位素的含意

进行这项研究主要是为了了解控制拉姆萨尔地区226 Ra异常的水文地球化学过程。分析揭示了两种类型的水:(1)非热Ca–HCO 3类型和(2)热Na–Cl类型,分别主要来自陨石和水热。由于硅酸盐的风化作用,非温泉的U浓度较高。温泉的特征在于高浓度的226 RA,即,铁,锂,铯,RB,锶,钡,B,溴-,F -,NO 3 -,PO 4 3-和SiO 2由高温水-罗斯克相互作用并与热液混合而产生。温泉是旧水热系统的表现形式,地下储层温度在83至100°C之间变化。镭活性是负的pH相关,与TDS,氯正相关- ,钡,和Ca,反映碱土金属的竞争性离子的影响,有Cl络合- ,和共沉淀用重晶石和方解石。这些过程被认为是控制泉水中226 Ra迁移率的主要因素。

更新日期:2021-03-27
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