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CVD graphene-based flexible and transparent SERS substrate towards L-tyrosine detection
Microelectronic Engineering ( IF 2.3 ) Pub Date : 2021-03-27 , DOI: 10.1016/j.mee.2021.111546
M. Emre Ayhan

The simple, rapid, reproducible, and sensitive detection of trace amounts of molecules is of great interest in terms of early diagnosis of diseases and food safety in daily-life applications. In this study, low-pressure chemical vapor deposited (LP-CVD) graphene(G)-based flexible and transparent AgNPs/CVDG@AryLite™ nanostructured surface enhanced Raman scattering (SERS) substrate has been demonstrated towards the detection of L-Tyrosine (L-Tyr) amino acid molecules. The synthesize of high-quality, single-crystal monolayer graphene films was achieved with considerably low (62.81 Ω sq.−1) sheet resistance and 94% transmittance at 550 nm wavelength. AgNPs are uniformly formed with a size distribution of about 60 nm on the CVDG surface. The fabricated substrates have been investigated by Rhodamine 6G (R6G) as probe molecule and L-Tyr amino acid molecules with different concentrations to understand the SERS properties. Significant enhancement of R6G and L-Tyr on the fabricated AgNPs/CVDG@AryLite™ SERS substrates obtained even if the 10−8 M R6G and L-Tyr solutions are used. The enhancement factors (EFs) are calculated as 109 and 7.5 × 109 for R6G and L-Tyr, respectively. The results in this research show that the fabricated nanostructured SERS substrates might open up a new path to design flexible and transparent optoelectronic devices towards detection of trace amount of molecules particularly portable spectroscopic instruments.



中文翻译:

基于CVD石墨烯的柔性和透明SERS底物,用于L-酪氨酸检测

在日常生活中疾病的早期诊断和食品安全方面,简单,快速,可重现和灵敏的痕量分子检测引起了人们的极大兴趣。在这项研究中,基于低压化学气相沉积(LP-CVD)石墨烯(G)的柔性和透明AgNPs / CVDG @ AryLite™纳米结构表面增强拉曼散射(SERS)基板已被证明可用于检测L-酪氨酸( L-Tyr)氨基酸分子。以相当低的(62.81Ωsq。-1)薄层电阻和550 nm波长下94%的透光率。AgNP在CVDG表面上以约60nm的尺寸分布均匀地形成。用罗丹明6G(R6G)作为探针分子和不同浓度的L-Tyr氨基酸分子对制备的底物进行了研究,以了解SERS特性。即使使用10 -8 M R6G和L-Tyr溶液,在获得的AgNPs / CVDG @ AryLite™SERS衬底上,R6G和L-Tyr也会显着提高。增强因子(EFs)计算为10 9和7.5×10 9分别用于R6G和L-Tyr。这项研究的结果表明,所制造的纳米结构的SERS衬底可能为设计用于检测痕量分子(尤其是便携式光谱仪器)的灵活而透明的光电设备开辟一条新途径。

更新日期:2021-04-01
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