当前位置: X-MOL 学术Heterocycles › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Copper Corrole Catalyzed Esterification of C(sp
Heterocycles ( IF 0.6 ) Pub Date : 2021-03-24 , DOI: 10.3987/com-21-14408
Hai-Yang Liu , Zhao-Yang Liu , Wei-Yu Peng , Waseem Akram , Jia-Wei Lai , Hao Zhang

Copper corrole complex was firstly used as catalyst for oxidative esterification of un-reactive C(sp3)-H bond of cyclic ether and carboxylic acid via cross dehydrogenative coupling (CDC) reaction using di-tert-butyl peroxide (DTBP) as oxidant. A wide range of carboxylic acids can react with cyclic ether with good to excellent yields, showing copper corrole is a new kind of promising catalyst for CDC reaction. Under gram-level test, the turnover number (TON) may achieve 8400 with 84% yield at only 0.01% catalyst loading, demonstrating its practical uses.

中文翻译:

铜Corrole催化的C(sp

铜络合物首先被用作催化剂,通过使用过氧化二叔丁基(DTBP)的交叉脱氢偶联(CDC)反应,将环醚和羧酸的非反应性C(sp 3 )-H键氧化酯化各种各样的羧酸都可以与环醚反应,具有良好或优异的收率,这表明铜盐是CDC反应的一种有希望的新型催化剂。在克级测试下,仅以0.01%的催化剂负载量,周转数(TON)即可达到8400,收率达到84%,这证明了其实际用途。
更新日期:2021-05-27
down
wechat
bug