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A readily accessible porous organic polymer facilitates high-yielding Knoevenagel condensation at room temperature both in water and under solvent-free mechanochemical conditions
Catalysis Communications ( IF 3.7 ) Pub Date : 2021-03-13 , DOI: 10.1016/j.catcom.2021.106304
Parishmita Sarma , Kashyap Kumar Sarmah , Dharittri Kakoti , Sanjeev Pran Mahanta , Nadeesh Madusanka Adassooriya , Goutam Nandi , Pranab Jyoti Das , Dejan-Krešimir Bučar , Ranjit Thakuria

A novel nitrogen-rich amorphous porous organic polymer has been synthesized using a microwave-assisted process. Its high chemical stability, reusability and poor solubility enable the use of the porous polymer as a metal-free heterogeneous catalyst for Csingle bondC bond formation at ambient temperature under environmentally benign conditions.



中文翻译:

易于获得的多孔有机聚合物有助于在水中和无溶剂机械化学条件下于室温下高收率的Knoevenagel缩合

使用微波辅助方法合成了一种新型的富氮无定形多孔有机聚合物。它的高化学稳定性,可重复使用性和较差的溶解度使该多孔聚合物可用作无金属的非均相催化剂,可单键在环境温度良好的环境条件下形成C C键。

更新日期:2021-03-22
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