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Optimized formulation of thermoresponsive nanoemulsion-based gel for enhanced oil recovery (EOR) application
Applied Petrochemical Research Pub Date : 2021-03-11 , DOI: 10.1007/s13203-021-00269-9
Natália Cristina Dalibera , Maria Helena Ambrosio Zanin , Kleber Lanigra Guimaraes , Leonardo Alencar de Oliveira , Adriano Marim de Oliveira

A thermoresponsive system of a nanoemulsion-based gel with favorable characteristics to enhanced oil recovery (EOR) application is presented. A full factorial design study with different formulations of thermosensitive nanoemulsion-based gels was performed to assess the influence of the oil chain length, concentration of polyethylene glycol (PEG 400) and concentration of oil on the rheological behavior of the system. A formulation with low viscosity at room temperature and high viscosity at the temperature of the oil extraction well was presented. Hexane (6-carbon chain), capric acid (10-carbon chain) and isopropyl myristate (17-carbon chain) were used in concentrations of 5%, 10%, 15% and 20% wt%, also varying the concentration of PEG 400 in 0%, 3%, 6% and 9% wt%. The thermosensitive polymer used was a mixture of Pluronic® F-127 and Pluronic® F-68 6:1 wt% at 4.7% concentration. The surfactants used were Tween 80 and Span 80 (HLB = 13) at 20%. The formulation containing 20% isopropyl myristate (IPM) without the addition of PEG 400 showed a better response, with an increase in viscosity of more than 38 times in relation to its viscosity at 25 °C, and the maximum viscosity was reached at 53 °C. This is a promising formulation for EOR technology.



中文翻译:

热响应性纳米乳液基凝胶的优化配方,可提高采油率(EOR)应用

提出了基于纳米乳液的凝胶的热响应系统,其具有对提高采油率(EOR)应用有利的特性。对热敏性纳米乳液基凝胶的不同配方进行了全因子设计研究,以评估油链长度,聚乙二醇(PEG 400)浓度和油浓度对系统流变行为的影响。提出了在室温下具有低粘度而在采油井的温度下具有高粘度的制剂。使用己烷(6-碳链),癸酸(10-碳链)和肉豆蔻酸异丙酯(17-碳链)时,其浓度分别为5%,10%,15%和20%wt%,也改变了PEG的浓度400的0%,3%,6%和9%wt%。使用的热敏聚合物是Pluronic的混合物® F-127和Pluronic ® F-68 6:1%(重量)在4.7%的浓度。所使用的表面活性剂为20%的Tween 80和Span 80(HLB = 13)。不含PEG 400的含20%肉豆蔻酸异丙酯(IPM)的配方表现出更好的响应,相对于其在25°C时的粘度,其粘度增加了38倍以上,并且在53°C时达到了最大粘度C。这是提高采收率技术的有希望的公式。

更新日期:2021-03-11
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