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On the Role of Competing Interactions in Charged Colloids with Short-Range Attraction
Annual Review of Condensed Matter Physics ( IF 22.6 ) Pub Date : 2021-03-10 , DOI: 10.1146/annurev-conmatphys-061020-053046
José Ruiz-Franco 1, 2 , Emanuela Zaccarelli 1, 2
Affiliation  

In this review, we discuss recent advances in the investigation of colloidal systems interacting via a combination of short-range attraction and long-range repulsion. The prototypical examples of this phenomenology are charged colloids with depletion interactions, but the results apply, to a large extent, also to suspensions of globular proteins, clays, and, in general, to systems with competing attractive (hydrophobic) and repulsive (polar) contributions. After a brief introduction to the problem, we focus on the three disordered states that characterize these systems: equilibrium cluster phase, equilibrium gel, and Wigner glass of clusters. We provide a comparison of their static and dynamic observables, mainly by means of numerical simulations. Next, we discuss the few available studies on their viscoelastic properties and on their response to an external shear. Finally, we provide a summary of the current findings and also raise the main open questions and challenges for the future in this topic.

中文翻译:


关于短程吸引带电胶体中竞争相互作用的作用

在这篇综述中,我们讨论了通过短程吸引和长程排斥相结合的胶体系统相互作用研究的最新进展。这种现象学的典型例子是带电荷的胶体,具有耗尽相互作用,但结果在很大程度上也适用于球状蛋白质,粘土的悬浮液,并且通常还适用于具有竞争性吸引力(疏水性)和排斥性(极性)的系统贡献。在简要介绍了该问题之后,我们将重点介绍表征这些系统的三个无序状态:平衡簇相,平衡凝胶和Wigner簇玻璃。我们主要通过数值模拟来比较它们的静态和动态观测值。下一个,我们讨论了有关粘弹性和对外部剪切的响应的一些现有研究。最后,我们总结了当前的发现,并提出了本主题中未来主要的开放性问题和挑战。

更新日期:2021-03-10
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