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Leaching characteristics and stability assessment of sequestered arsenic in flue dust based glass
Chemosphere ( IF 8.8 ) Pub Date : 2021-03-03 , DOI: 10.1016/j.chemosphere.2021.130173
Harshit Mahandra , Chengqian Wu , Ahmad Ghahreman

Arsenic (As), a toxicant, present in flue dust, tailings, and mine drainages generated from mineral processing and smelting processes represents high environmental risk due to its high mobility. Around 42–50% As is found in flue dust in the form of As2O3. The vitrification of As results in the formation of stable inert glass material and supposed to reduce the risk of As release to the environment. In this study, a glass material produced by vitrification of As bearing flue dust via DST GlassLock™ Process was received from Dundee Sustainable Technologies, Canada and was subjected for As stability assessment using United States Environmental Protection Agency (EPA) leaching methods-1311,1312,1313,1314,1315 and 1316. The released arsenic concentration was found to be less than the recommended TCLP hazardous waste limit for arsenic i.e., 5 mg/L in most of the test conditions. The experimental data were analyzed using LeachXS Lite™, a data management software that showed the goodness of the DST GlassLock™ Process for As stabilization and safe landfill deposition of the resulting product.



中文翻译:

烟尘基玻璃中螯合砷的浸出特性和稳定性评估

矿物加工和冶炼过程中产生的烟尘,尾矿和矿井排水中存在的砷(As)是一种有毒物质,由于其高迁移率而具有很高的环境风险。在烟道粉尘中以As 2 O 3的形式存在约42–50%的As。砷的玻璃化导致形成稳定的惰性玻璃材料,并应减少砷向环境中释放的风险。在这项研究中,从加拿大邓迪可持续技术公司获得了通过DST GlassLock™工艺将含砷烟道粉尘玻璃化的玻璃材料,并使用美国环境保护局(EPA)淋溶方法对其进行了砷稳定性评估-1311,1312。 ,1313、1314、1315和1316。发现释放的砷浓度低于建议的TCLP有害砷限量建议限值,即在大多数测试条件下为5 mg / L。使用LeachXS Lite™(一种数据管理软件)对实验数据进行了分析,该软件显示了DST GlassLock™工艺对于As稳定化和最终产品的安全垃圾填埋的好处。

更新日期:2021-03-10
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