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Low-medium temperature application of selective catalytic reduction denitration in cement flue gas through a pilot plant
Chemosphere ( IF 8.8 ) Pub Date : 2021-03-03 , DOI: 10.1016/j.chemosphere.2021.130182
Yangyang Guo , Lei Luo , Yang Zheng , Jian Wang , Tingyu Zhu

Low-medium temperature application of selective catalytic reduction (SCR) denitration in cement flue gas was established and investigated in this study. The 2000h continuous operation shows the concentration of NOx at the outlet can be maintained at 24 mg/Nm3 on average, while due to the increase of SO2 in flue gas, the NOx concentration increased to 57.5 mg/Nm3 after long time operation. The sulfur deposition is the main reason for catalyst deactivation, and SO2 is still a big obstacle for low-medium temperature SCR application in cement flue gas. The denitration efficiency was tested as fluctuated from 73.5% to 86.2%, and ammonia concentration after SCR was as still as high as 22.5∼60.0 mg/Nm3 due to the excessive ammonia injection from selective non-catalytic reduction (SNCR), shows serious ammonia escape problem for SNCR, and the potential application of hybrid SNCR-SCR technology. In order to maintain the denitration efficiency above 85%, the gaseous hourly space velocity (GHSV) should not be exceeded 2800 h-1, the electrostatic precipitators (ESP) setting at 60 kV was relatively appropriate, the temperature of the flue gas should be kept at above 200°C. The concentrations and toxic equivalent quantities (TEQs) of the PCDD/Fs congeners in the flue gas raised greatly after SCR reactor, indicating the PCDD/Fs concentration should be concerned during the application of low-medium temperature SCR, especially for the waste co-disposal processes.



中文翻译:

通过中试工厂在水泥烟气中选择性催化还原脱硝的中低温应用

建立并研究了水泥烟气中选择性催化还原(SCR)脱硝的中低温应用。在2000H连续操作显示NO的浓度X在出口处可保持在24毫克/牛顿米3的平均值,而由于SO增加2的烟道气中时,NO X浓度增加至57.5毫克/牛顿米3长后时间操作。硫沉积是催化剂失活的主要原因,而SO 2仍然是水泥烟气中低温SCR应用的一大障碍。测试了脱硝效率从73.5%波动至86.2%,由于选择性非催化还原(SNCR)过量注入氨,SCR后的氨浓度仍高达22.5〜60.0 mg / Nm 3,显示出严重的SNCR的氨逃逸问题,以及混合SNCR-SCR技术的潜在应用。为了使脱硝效率保持在85%以上,气态时空速度(GHSV)不应超过2800 h -1,将静电除尘器(ESP)设置为60 kV比较合适,烟气温度应保持在200°C以上。SCR反应器后烟道气中PCDD / Fs同系物的浓度和毒性当量(TEQs)大大增加,这表明在中低温度SCR的应用中应特别关注PCDD / Fs的浓度,特别是对于废渣处置过程。

更新日期:2021-03-21
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