Two new layered barium perrhenate halides, BaX(ReO₄) (X = Cl and Br), were prepared and their structures were refined from single-crystal and powder data, respectively. Both compounds are isostructural to the previously reported BaCl(MnO₄), exhibiting a matlockite (PbFCl)-derived motif. The structure of previously reported PbBr(ReO₄) was also refined, in order to obtain a complete data set; it is similar to PbCl(ReO₄). The structures of Ba and Pb compounds correspond to the centro- and non-centrosymmetric versions (pseudo-polymorphs) of the same motif corresponding to the alternation of [M₂X₂]²⁺ litharge-derived slabs and double sheets of perrhenate anions. Strong relationships exist to the structures of LnX(TO₄) (X = Cl, Br; T = Mo, W) which are monoclinically distorted versions of the orthorhombic permanganates and perrhenates. Crystal chemistry and further perspectives of the compounds with litharge slabs constructed of Cl, Br, and I-centered tetrahedra are discussed.

制备了两种新的层状高r酸钡卤化物Ba X（ReO ₄）（X  = Cl和Br），并分别从单晶和粉末数据中精炼了它们的结构。两种化合物都与先前报道的BaCl（MnO ₄）具有同构结构，表现出由菱锰矿（PbFCl）衍生的基序。为了获得完整的数据集，还对先前报道的PbBr（ReO ₄）的结构进行了改进。它类似于PbCl（ReO ₄）。Ba和Pb化合物的结构对应于同一主题的中心和非中心对称形式（伪多晶型物），对应于[ M ₂ X ₂ ] ²⁺的交替源自立陶宛的平板和双层高ate酸根阴离子。Ln X（T O ₄）（X  = Cl，Br; T  = Mo，W）的结构具有很强的关系，它们是正交晶体的高锰酸盐和高r酸盐的单临床畸变形式。讨论了晶体化学以及具有由Cl，Br和I中心的四面体构成的轻晶平板的化合物的进一步观点。