当前位置: X-MOL 学术Can. J. Chem. Eng. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Preparation of silicon-based soybean base oil by modified soybean oil by transesterification and hydrosilation
The Canadian Journal of Chemical Engineering ( IF 2.1 ) Pub Date : 2021-02-26 , DOI: 10.1002/cjce.24093
Xiaobin Zhu 1 , Zhi Yun 1 , Xia Gui 1
Affiliation  

A new green lubricating base oil was synthesized from soybean oil and triethyl silane by a combination of transesterification and hydrosilylation. The factors affecting the process of hydrosilylation were thoroughly investigated. AlCl3/C catalyst as catalyst for hydrosilylation showed better catalytic performance, and a higher yield of 36.79% was obtained under optimal condition of molar ratio of transesterified soybean oils/triethyl silane (1:1.1), reaction temperature 120°C, and reaction time 8 h. In addition, the performance of silicon-based soybean base oil was tested according to industry standards. Compared with soybean oil, silicon-based soybean base oil was obtained with high viscosity index, good pour point of −17°C, and excellent wear characteristic.

中文翻译:

酯交换和硅氢化改性大豆油制备硅基大豆基础油

以大豆油和三乙基硅烷为原料,通过酯交换和氢化硅烷化反应合成了一种新型绿色润滑油基础油。彻底研究了影响氢化硅烷化过程的因素。AlCl 3 /C催化剂作为氢化硅烷化的催化剂表现出较好的催化性能,在酯交换豆油/三乙基硅烷摩尔比为1:1.1、反应温度120℃、反应条件为最佳条件下,产率高达36.79%。时间 8 小时。此外,硅基大豆基础油的性能也按照行业标准进行了测试。与大豆油相比,硅基大豆基础油具有高粘度指数、-17°C的良好倾点和优异的耐磨特性。
更新日期:2021-02-26
down
wechat
bug