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Influence of different sources of cerium on the oxidation-reduction ability and oxygen vacancies of CeO2-MnOx in the catalytic oxidation of toluene
Surfaces and Interfaces ( IF 6.2 ) Pub Date : 2021-02-26 , DOI: 10.1016/j.surfin.2021.101042
Zhongxian Song , Yuanhang Wei , Zi'ang Ma , Xuejun Zhang , Yanli Mao , Jiawen Luo , Xinfeng Zhu , Wei Liu , Junjie Jin

The catalytic oxidation of toluene was investigated over CeO2-MnOx catalysts with the different cerium sources. The CeO2-MnOx catalyst synthesized by ceric ammonium nitrate (marked as Cat-A) possessed the superior catalytic performance among the samples. Notably, the synergistic effect between CeO2 and MnOx could provide more amounts of oxygen vacancy, the highest concentration of Mn3+ and the highest Ce3+ contents, which resulted in the outstanding oxygen mobility, causing the improvement of catalytic activity. In brief, the catalytic performance of CeO2-MnOx was closely related to the different modulation cerium sources during the preparation process.



中文翻译:

铈的不同来源对甲苯催化氧化中CeO 2 -MnO x的氧化还原能力和氧空位的影响

在铈源不同的CeO 2 -MnO x催化剂上研究了甲苯的催化氧化。硝酸铈铵合成的CeO 2 -MnO x催化剂(标记为Cat-A)在样品中具有优异的催化性能。值得注意的是,CeO 2和MnO x之间的协同作用可以提供更多的氧空位,最高的Mn 3+浓度和最高的Ce 3+含量,从而导致出色的氧迁移率,从而提高了催化活性。简而言之,CeO 2 -MnO x的催化性能 在制备过程中与不同的调制铈源密切相关。

更新日期:2021-03-03
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