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Roles of Y and Fe contents on glass-forming ability, thermal stability, and magnetic properties of Co-based Co–Fe–Y–B bulk metallic glasses
Intermetallics ( IF 4.4 ) Pub Date : 2021-02-26 , DOI: 10.1016/j.intermet.2021.107135
Xinyu Liang , Yanhui Li , Feng Bao , Zhengwang Zhu , Haifeng Zhang , Wei Zhang

Soft magnetic Co-based bulk metallic glasses (BMGs) with large supercooled liquid region (ΔTx) and high saturation magnetic flux density (Bs) have been developed in a new Co–Fe–Y–B alloy system. Addition of appropriate contents of Y and Fe into a Co75B25 alloy enlarges the ΔTx and improves the glass-forming ability (GFA). ΔTx of 50–64 K and a critical diameter of up to 2.0 mm have been achieved for the (Co0.5–0.7Fe0.3–0.5)71.5Y3.5B25 BMGs. The coercivity (Hc) of Co75-xYxB25 and (Co0.7Fe0.3)75-xYxB25 (x = 0–5) alloy series shows a similar V-shape change with Y content, and gets the minimum at x = 3.5, while that of (Co1-yFey)71.5Y3.5B25 (y = 0–0.5) alloys keeps rising with the increase of Fe content. The Bs of the alloys monotonically decreases with more Y addition and increases with enriching of Fe. The (Co0.5–0.7Fe0.3–0.5)71.5Y3.5B25 BMGs exhibit high Bs of 1.00–1.17 T and low Hc of 5.4–6.4 A/m. The BMGs possess high yield strength of 3978–4152 MPa with distinct plastic strain of up to 0.9% and Vickers hardness of 1218–1233 as well. The possible mechanisms of Y and Fe affecting the GFA, thermal stability, and magnetic properties of the Co-based Co–Fe–Y–B metallic glasses have been discussed.



中文翻译:

Y和Fe含量对Co基Co–Fe–Y–B块状金属玻璃的玻璃形成能力,热稳定性和磁性能的影响

在新的Co–Fe–Y–B合金系统中,已经开发出具有大的过冷液体区域(ΔT x)和高饱和磁通密度(B s)的软磁Co基块状金属玻璃(BMG)。在Co 75 B 25合金中添加适当含量的Y和Fe可增加ΔT x并改善玻璃形成能力(GFA)。Δ Ť X 50-64的K和高达2.0mm的临界直径已被用于(共实现0.5-0.7的Fe 0.3-0.571.5 Ý 3.525非晶合金。Co的矫顽力(H c75-x Y x B 25和(Co 0.7 Fe 0.375-x Y x B 25(x = 0-5)合金系列显示出类似的V形随Y含量的变化,并在x = 3.5时达到最小值, (Co 1-y Fe y71.5 Y 3.5 B 25(y = 0-0.5)合金的含量随着Fe含量的增加而不断提高。所述小号合金的单调以上的Y加法和增加与铁的富集减小。(Co 0.5-0.7 Fe 0.3-0.571.5 Y 3.5 B25个BMG具有1.00–1.17 T的高B s和5.4–6.4 A / m的低H c。BMG具有3978–4152 MPa的高屈服强度,高达0.9%的独特塑性应变以及1218–1233的维氏硬度。讨论了Y和Fe影响Co基Co-Fe-Y-B金属玻璃的GFA,热稳定性和磁性能的可能机理。

更新日期:2021-02-26
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