Organic Materials Pub Date : 2021-02-24 , DOI: 10.1055/s-0041-1723020 Eric R. Wolfson 1 , Erica M. Moscarello 1 , William K. Haug 1 , Psaras L. McGrier 1
Covalent organic frameworks (COFs) are an advanced class of crystalline porous polymers that have garnered significant interest due to their tunable properties and robust molecular architectures. As a result, COFs with energy-storage properties are of particular interest to the field of rechargeable battery electrode materials. However, investigation into COFs as candidates for energy-storage materials is still in its infancy. This review will highlight methods used to fabricate COFs used as electrode materials and discuss the factors that prove critical for their production. A collection of known COF-based energy-storage systems will be featured. In addition, the ability to utilize the storage properties of COFs for systems beyond traditional Li-ion batteries will be addressed. An outlook will address the current progress and remaining challenges facing the field to ultimately expand the scope of their applications.
中文翻译:
共价有机框架作为可充电电池的电极材料
共价有机骨架(COF)是一类高级的晶体多孔聚合物,由于其可调性和坚固的分子结构,它们引起了人们的极大兴趣。结果,具有能量存储特性的COF是可再充电电池电极材料领域中特别感兴趣的。但是,对作为储能材料候选材料的COF的研究仍处于起步阶段。这篇综述将重点介绍用于制造用作电极材料的COF的方法,并讨论证明对其生产至关重要的因素。将展示一组基于COF的已知储能系统。此外,还将解决利用COF的存储特性为传统锂离子电池以外的系统提供服务的能力。