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Structural and low-temperature magnetic properties of as-quenched and annealed Ni–Si–B alloys produced by rapid solidification
Intermetallics ( IF 4.4 ) Pub Date : 2021-02-23 , DOI: 10.1016/j.intermet.2021.107140
M. Ipatov , V. Zhukova , L. Dominguez , K.L. Alvarez , A. Chizhik , A. Zhukov , J. Gonzalez

Structural characterization (differential scanning calorimetry, DSC, and X-ray diffraction, XRD) and temperature dependence of the magnetization are reported in Ni80Si10B10 and Ni75Si15B10 alloy ribbons produced by rapid solidification. XDR and DSC measurements lead to confirm the amorphous character of Ni75Si15B10 alloy while the Ni80Si10B10 alloy presents a mixture of amorphous and crystalline (Nickel face-centered cubic) phase. Low-temperature magnetization dependencies were analyzed in terms of spin-wave excitation and fluctuations of the exchange interaction. While both mechanisms are relevant for the high Ni-content alloy, fluctuations of exchange could be ascribed as mechanism for low Ni-content alloy. The effect of annealing (523 and 623 K during 1 h) on the magnetic behavior is also presented. Thus, annealing of Ni75 sample at 623 K also results in appearance of highly magnetic Ni phase.



中文翻译:

快速凝固产生的淬火和退火Ni-Si-B合金的结构和低温磁性能

在通过快速凝固制备的Ni 80 Si 10 B 10和Ni 75 Si 15 B 10合金薄带中,报道了磁化强度的结构表征(差示扫描量热法,DSC和X射线衍射,XRD)和温度依赖性。XDR和DSC测量可确定Ni 75 Si 15 B 10合金的非晶态特性,而Ni 80 Si 10 B 10的非晶态特性合金呈现出非晶态和晶态(镍面心立方)相的混合物。根据自旋波激发和交换相互作用的波动分析了低温磁化依赖性。虽然两种机理都与高Ni含量合金有关,但是交换的波动可以归因于低Ni含量合金。还介绍了退火(1小时内的523和623 K)对磁性能的影响。因此,Ni75样品在623 K退火也导致出现高磁性的Ni相。

更新日期:2021-02-23
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