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Highly efficient and selectivity removal of heavy metal ions using single-layer NaxKyMnO2 nanosheet: A combination of experimental and theoretical study
Chemosphere ( IF 8.8 ) Pub Date : 2021-02-22 , DOI: 10.1016/j.chemosphere.2021.130068
Ruichao Peng , Hao Li , Yongting Chen , Feipeng Ren , Fengyu Tian , Yawei Gu , Honglei Zhang , Xiurong Huang

Manganese oxides (MnO2) are widely applied in heavy metal ions removal due to their low-cost, environmental-friendly and biocompatibility. However, the adsorption capacity of MnO2 need to be further improved to satisfy the demand of practical application. Herein, a highly dispersed single layer NaxKyMnO2 nanosheet was synthesized by a facile wet-chemical method with sodium dodecyl sulfonate as surfactant. The high surface specific area, excellent dispersibility and abundant oxygen vacancies endowed NaxKyMnO2 nanosheets with potential in heavy metal ions adsorption. The adsorption experiments results showed that NaxKyMnO2 nanosheets possessed high efficiency and selectivity towards lead ion (Pb2+) with a high adsorption capacity of 2091.8 μmol g−1. The NaxKyMnO2 also showed an excellent reusability with the removal rate of 95.4% for Pb2+ even after five cycles. Moreover, both the theoretical calculation and experimental data illustrated that the single layer NaxKyMnO2 nanosheets possess high selectivity to Pb2+ adsorption.



中文翻译:

使用单层Na x K y MnO 2纳米片高效和选择性地去除重金属离子:实验和理论研究的结合

锰氧化物(MnO 2)由于其低成本,环保和生物相容性而被广泛应用于重金属离子的去除。然而,需要进一步提高MnO 2的吸附能力以满足实际应用的需求。在此,以十二烷基磺酸钠为表面活性剂,通过简便的湿化学法合成了高度分散的Na x K y MnO 2单层纳米片。高比表面积,出色的分散性和丰富的氧空位使Na x K y MnO 2纳米片具有重金属离子吸附的潜力。吸附实验结果表明,Na xK y MnO 2纳米片具有较高的效率和对铅离子(Pb 2+)的选择性,并具有2091.8μmolg -1的高吸附容量。Na x K y MnO 2也显示出极好的可重复使用性,即使经过五个循环,对Pb 2+的去除率也达到95.4%。此外,理论计算和实验数据均表明,单层Na x K y MnO 2纳米片具有对Pb 2+吸附的高选择性。

更新日期:2021-03-04
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