Energy shortages and climate change call for the development of clean and sustainable energy. The development of green materials for clean energy storage and conversion is conducive to promoting the widespread use of clean energy. Conjugated microporous polymers (CMPs) have been synthesized with various structures and properties, which offer designability for the molecular structures and nanopores of conjugated skeletons. The research of CMPs in clean energy technologies is significant for the improvement of CMP-based materials and their application in energy and environmental engineering. CMPs have shown great potential for challenging energy and environmental issues such as gas adsorption, photocatalysis, solar energy conversion, and electrical energy storage and conversion. This review aims to summarize the advances of synthesis and design on CMPs, computer simulations on CMPs, and the applications of CMPs in the clean energy technologies including hydrogen evolution and storage, the adsorption and conversion of carbon dioxide, rechargeable batteries, supercapacitors, fuel cells, and photovoltaic cells. We also propose the challenges and potential chances of the synthesis and the clean energy applications of CMPs.

能源短缺和气候变化要求发展清洁和可持续的能源。用于清洁能源存储和转化的绿色材料的发展有利于促进清洁能源的广泛使用。已经合成了具有各种结构和性质的共轭微孔聚合物（CMP），这为共轭骨架的分子结构和纳米孔提供了可设计性。清洁能源技术中CMP的研究对于改进CMP基材料及其在能源和环境工程中的应用具有重要意义。CMP在挑战能源和环境问题方面显示出巨大潜力，例如气体吸附，光催化，太阳能转化以及电能存储和转化。这篇综述旨在总结CMP的合成和设计，CMP的计算机模拟以及CMP在清洁能源技术中的应用，这些技术包括氢气的产生和存储，二氧化碳的吸附和转化，可充电电池，超级电容器，燃料电池和光伏电池。我们还提出了CMP的合成和清洁能源应用的挑战和潜在机会。