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Orange-red emitting praseodymium doped yttrium-molybdate nanophosphors for multifunctional applications
Journal of Science: Advanced Materials and Devices ( IF 7.382 ) Pub Date : 2021-02-17 , DOI: 10.1016/j.jsamd.2021.02.002
K.R. Bhagya , K.R. Jyothi , Vinayakprasanna N. Hegde , B. Daruka Prasad , H. Nagabhushana , S.C. Sharma , N.M. Nagabhushana

Orange-red emitting praseodymium (Pr3+) activated yttrium molybdenum oxide (Y2MoO6) nanophosphors (NPs) were synthesized via low-temperature solution combustion method using Aloe vera gel as a surfactant and fuel. The synthesized NPs were subjected to structural, morphological, optical, and electrical studies. The powder X-ray diffraction (PXRD) study reveals that the Y2MoO6 composite consists of a monoclinic crystal phase. Peak shift to the left side was observed with increase in the doping concentration of Pr3+ ions into the crystal system, which is attributed to the strain. Foamy type morphology was revealed from scanning electron microscope studies, whereas the nanostructural features of the samples were confirmed by both transmission electron microscope and PXRD. From the diffused reflectance spectroscopy study, the optical band gap was estimated to be in the range of 3.36–3.48 eV. Fourier transforms infrared spectroscopy was used to identify the metal oxygen bonds along with the other types of bonds if any. The AC conductivity and dielectric properties were measured in the frequency range of 100 Hz–5 MHz. The photoluminescence (PL) studies revealed the characteristic of emission peaks of Pr3+ ions. The Commission International de l'Eclairage (CIE) coordinates were located in orange-red color. The average correlated color temperature analysis indicates that the Y2MoO6:Pr3+ NPs can be useful for use in warm light sources. The Y2MoO6: Pr3+ (5 mol%) NPs were used for the design of anti-counterfeiting ink in security applications. The tunable properties of the prepared Y2MoO6:Pr3+ NPs make them suitable for multifunctional applications.



中文翻译:

橙红色发射emitting掺杂钼酸钇纳米荧光粉,用于多功能应用

芦荟胶为表面活性剂和燃料为原料,通过低温溶液燃烧法合成了橙红色发光P(Pr 3+)活化钇钼氧化物(Y 2 MoO 6)纳米磷光体(NPs)。对合成的NP进行结构,形态,光学和电学研究。粉末X射线衍射(PXRD)研究表明,Y 2 MoO 6复合材料由单斜晶相组成。随着Pr 3+的掺杂浓度增加,向左移动。离子进入晶体系统,这归因于应变。扫描电子显微镜研究揭示了泡沫类型的形态,而透射电子显微镜和PXRD证实了样品的纳米结构特征。根据漫反射光谱研究,光学带隙估计在3.36–3.48 eV的范围内。使用傅立叶变换红外光谱法来鉴定金属氧键以及其他类型的键(如果有)。在100 Hz-5 MHz的频率范围内测量了交流电导率和介电性能。光致发光(PL)研究揭示了Pr 3+的发射峰的特征离子。国际照明委员会(CIE)的坐标为橙红色。平均相关色温分析表明,Y 2 MoO 6:Pr 3+ NP可用于暖光源。Y 2 MoO 6:Pr 3+(5 mol%)NP用于安全应用中的防伪油墨设计。制备的Y 2 MoO 6:Pr 3+ NP的可调谐特性使其适用于多功能应用。

更新日期:2021-02-17
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